钯催化烯丙醇的胺化反应。
Palladium-catalyzed amination of allyl alcohols.
机构信息
Department of Organic Chemistry, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700032, India.
出版信息
J Org Chem. 2011 Oct 21;76(20):8508-12. doi: 10.1021/jo2014438. Epub 2011 Sep 21.
PMID:21892817
Abstract
An efficient catalytic amination of aryl-substituted allylic alcohols has been developed. The complex (η(3)-allyl)PdCl modified by a bis phosphine ligand, L, has been used as catalyst in the reaction that afforded a wide range of allyl amines in good to excellent yield under mild conditions.
摘要
一种高效的芳基取代烯丙醇的催化胺化反应已经被开发出来。该反应使用了一种双膦配体 L 改性的 (η(3)-allyl)PdCl 作为催化剂，在温和条件下能够以良好到优秀的收率得到广泛的烯丙基胺。
Zotero 插件