高效且高选择性的铁催化硝基芳烃还原反应。
Efficient and highly selective iron-catalyzed reduction of nitroarenes.
机构信息
Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany.
出版信息
Chem Commun (Camb). 2011 Oct 21;47(39):10972-4. doi: 10.1039/c1cc13728j. Epub 2011 Sep 7.
PMID:21897952
Abstract
Pyrolysis of iron-phenanthroline complexes supported on carbon leads to highly selective catalysts for the reduction of structurally diverse nitroarenes to anilines in 90-99% yields. Excellent chemoselectivity for the nitro group reduction is demonstrated.
摘要
在碳载体上负载的铁-菲咯啉配合物的热解导致高选择性的催化剂，可将结构多样的硝基芳烃以 90-99%的收率还原为苯胺。该催化剂对硝基还原具有优异的化学选择性。
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