钯催化七富烯的 1,8-共轭加成反应通过双-π-烯丙基钯配合物。
Palladium catalyzed 1,8-conjugate addition to heptafulvene via bis-π-allyl palladium complexes.
机构信息
Organic Chemistry Section, Chemical Sciences and Technology Division, National Institute for Interdisciplinary Science and Technology (NIIST)-CSIR, Trivandrum 695019, India.
出版信息
Org Lett. 2011 Oct 7;13(19):4984-7. doi: 10.1021/ol202137m. Epub 2011 Sep 7.
PMID:21899322
Abstract
The palladium catalyzed 1,8-conjugate addition of heptafulvene, an antiaromatic conjugated 8π-electron system, is discussed. The method is utilized for the concise synthesis of bis-functionalized cycloheptatriene (CHT) derivatives. This is the first report on the palladium catalyzed bisfunctionalization of a cyclic cross conjugated system.
摘要
钯催化的庚富烯（一种反芳香共轭 8π-电子体系）的 1,8-共轭加成被讨论。该方法用于简洁合成双官能化环庚三烯（CHT）衍生物。这是首例关于钯催化的环状交叉共轭体系双官能化的报道。
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