Department of Chemistry, Texas A&M University, College Station, Texas 77843, USA.
Inorg Chem. 2011 Nov 7;50(21):10528-30. doi: 10.1021/ic201744n. Epub 2011 Sep 26.
A (3,24)-connected mesoporous metal-organic framework, PCN-69, was synthesized by linking a hexatopic ligand btti with dicopper paddlewheel clusters. This material has rigid connectivity but a flexible framework, which has been attributed to a curvature change of the ligand.
一种(3,24)连接的介孔金属有机骨架 PCN-69,通过连接六配位配体 btti 和双铜桨轮簇合成。该材料具有刚性连接但柔性骨架,这归因于配体的曲率变化。