Departamento de Física, Universidade Estadual de Maringá, Avenida Colombo 5790, 87020-900 Maringá, Paraná, Brazil.
J Chem Phys. 2011 Sep 21;135(11):114704. doi: 10.1063/1.3637944.
The electrical response of an electrolytic cell in which the diffusion of mobile ions in the bulk is governed by a fractional diffusion equation of distributed order is analyzed. The boundary conditions at the electrodes limiting the sample are described by an integro-differential equation governing the kinetic at the interface. The analysis is carried out by supposing that the positive and negative ions have the same mobility and that the electric potential profile across the sample satisfies the Poisson's equation. The results cover a rich variety of scenarios, including the ones connected to anomalous diffusion.
分析了扩散系数遵从分数阶扩散方程的电解池的电响应。通过积分微分方程来描述限制样品的电极边界条件,该方程控制着界面处的动力学过程。分析中假设正、负离子具有相同的迁移率,并且穿过样品的电势分布满足泊松方程。研究结果涵盖了丰富的场景,包括与反常扩散相关的场景。