氧化铈纳米团簇：符合多金属氧酸盐化学的概念？
Cerium oxide nanoclusters: commensurate with concepts of polyoxometalate chemistry?
机构信息
Institute of Inorganic Chemistry, RWTH Aachen University, 52070 Aachen, Germany.
出版信息
Chem Commun (Camb). 2012 Feb 1;48(10):1499-501. doi: 10.1039/c1cc14725k. Epub 2011 Sep 30.
PMID:21959980
Abstract
The mixed-valent cerium(III/IV) oxide clusters {Ce(10)} and {Ce(22)}, derived from condensation reactions of cerium carboxylate coordination polymers, exhibit molecular growth tendencies similar to those of 'classical' group V and VI polyoxometalates, but with increasing nuclearity approach the structure of the parental oxide, CeO(2).
摘要
混合价态铈（III/IV）氧化物簇 {Ce(10)} 和 {Ce(22)}，来源于铈羧酸酯配位聚合物的缩合反应，表现出与“经典”的第 V 和第 VI 多金属氧酸盐类似的分子生长趋势，但随着核数的增加，逐渐接近母体氧化物 CeO(2)的结构。
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