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利用大气微波空气等离子体处理空气中的石棉和类石棉微纤维颗粒。

Treatment of airborne asbestos and asbestos-like microfiber particles using atmospheric microwave air plasma.

机构信息

Department of Chemical Engineering, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152-8552, Japan.

出版信息

J Hazard Mater. 2011 Nov 15;195:405-13. doi: 10.1016/j.jhazmat.2011.08.062. Epub 2011 Aug 27.

Abstract

Atmospheric microwave air plasma was used to treat asbestos-like microfiber particles that had two types of ceramic fiber and one type of stainless fiber. The treated particles were characterized via scanning electron microscopy (SEM) and X-ray diffraction (XRD). The experiment results showed that one type of ceramic fiber (Alumina:Silica=1:1) and the stainless fiber were spheroidized, but the other type of ceramic fiber (Alumina:Silica=7:3) was not. The conversion of the fibers was investigated by calculating the equivalent diameter, the aspect ratio, and the fiber content ratio. The fiber content ratio in various conditions showed values near zero. The relationship between the normalized fiber vanishing rate and the energy needed to melt the particles completely per unit surface area of projected particles, which is defined as η, was examined and seen to indicate that the normalized fiber vanishing rate decreased rapidly with the increase in η. Finally, some preliminary experiments for pure asbestos were conducted, and the analysis via XRD and phase-contrast microscopy (PCM) showed the availability of the plasma treatment.

摘要

大气微波空气等离子体用于处理类似石棉的微纤维颗粒,这些颗粒由两种陶瓷纤维和一种不锈钢纤维组成。通过扫描电子显微镜(SEM)和 X 射线衍射(XRD)对处理后的颗粒进行了表征。实验结果表明,一种陶瓷纤维(氧化铝:二氧化硅=1:1)和不锈钢纤维呈球形化,但另一种陶瓷纤维(氧化铝:二氧化硅=7:3)则没有。通过计算等效直径、纵横比和纤维含量比来研究纤维的转化。在各种条件下,纤维含量比均接近零。考察了归一化纤维消失率与完全熔化单位投影颗粒表面积所需的能量(定义为 η)之间的关系,结果表明归一化纤维消失率随 η 的增加而迅速下降。最后,对纯石棉进行了一些初步实验,XRD 和相衬显微镜(PCM)的分析表明等离子体处理是可行的。

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