Faculty of Light Industry and Chemical Engineering, Guangdong University of technology, Ghuangzhou, China.
Dalton Trans. 2011 Nov 28;40(44):11693-5. doi: 10.1039/c1dt11366f. Epub 2011 Oct 10.
A new conformer of indium germanate InGe(3)O(7.5)(en) (denoted as δ-type), constructed with the flexible unit of In(2)Ge(6)O(15)N(2) was successfully prepared through a solvothermal method. The crystal data for the δ-type InGe(3)O(7.5)(en) are listed as follows: triclinic, space group P-1 (No.2), a = 7.826(4) Å, b = 8.287(3) Å, c = 9.224(4) Å, α = 71.887(17)°, β = 85.343(18)°, γ = 63.734(12)°, V = 508.64 Å(3), Z = 2. Four relevant conformers of indium germanate are compared with each other. The conformational polymorphism in the germanate family is reported for the first time.
一种新型的铟锗酸盐 InGe(3)O(7.5)(en)（表示为 δ 型），通过溶剂热法成功制备，其结构由柔性单元 In(2)Ge(6)O(15)N(2)构建。δ 型 InGe(3)O(7.5)(en)的晶体数据如下：三斜晶系，空间群 P-1（No.2），a = 7.826(4) Å，b = 8.287(3) Å，c = 9.224(4) Å，α = 71.887(17)°，β = 85.343(18)°，γ = 63.734(12)°，V = 508.64 Å(3)，Z = 2。将四种相关的铟锗酸盐构型进行了比较。首次报道了锗酸盐家族中的构象多态性。
