聚集体在自组装单分子层上的结晶。

Conglomerate crystallization on self-assembled monolayers.

机构信息

Department of Chemistry and the Institute of Nanotechnology Bar-Ilan University, Ramat-Gan 52900, Israel.

出版信息

Chem Commun (Camb). 2011 Nov 28;47(44):12161-3. doi: 10.1039/c1cc14952k. Epub 2011 Oct 11.

PMID:21986883

Abstract

In this communication, we demonstrate that chiral self-assembled monolayers can be used for polymorphism control of chiral crystals. We studied the crystallization of DL-glutamic acid on chiral self-assembled monolayers and showed that crystallization of DL-glutamic acid on the chiral SAMs resulted in stabilization of the metastable conglomerate form.

摘要

在本通讯中，我们证明手性自组装单分子层可用于控制手性晶体的多晶型现象。我们研究了 D/L-谷氨酸在手性自组装单分子层上的结晶行为，并表明 D/L-谷氨酸在手性 SAMs 上的结晶导致了亚稳聚集体形式的稳定化。