Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, Chiba 263-8522, Japan.
Chem Commun (Camb). 2011 Dec 14;47(46):12447-9. doi: 10.1039/c1cc15118e. Epub 2011 Oct 17.
A ditopic melamine bearing perylene bisimides with swallow-tail alkyl chains can be dissolved in organic solvents by mixing with complementary hydrogen-bonding barbiturate or cyanurate, forming solution processable supramolecular assemblies. Upon spin-coating the assemblies, highly organized lamellar architectures are formed with thermal annealing, which act as electron transporting layers in organic field effect transistors.
一种具有燕尾型烷基链的双齿三聚氰胺取代的苝二酰亚胺可以通过与互补氢键的巴比妥酸或氰尿酸混合溶解在有机溶剂中，形成可溶液加工的超分子组装体。通过旋涂组装体，并在热退火后形成高度有序的层状结构，该结构可用作有机场效应晶体管中的电子传输层。
