用于合成乙烯基环丁烷的环间 Claisen 重排反应：（±）-大根香叶醇的形式合成。
Transannular Claisen rearrangement reactions for the synthesis of vinylcyclobutanes: formal synthesis of (±)-grandisol.
机构信息
Department of Chemistry, Imperial College London, South Kensington Campus, London, UK SW7 2AZ.
出版信息
Org Biomol Chem. 2011 Dec 7;9(23):8000-2. doi: 10.1039/c1ob06619f. Epub 2011 Oct 20.
PMID:22011731
Abstract
Unsaturated eight-membered lactones undergo decarboxylative and non-decarboxylative transannular Ireland-Claisen rearrangement reactions, to give substituted vinylcyclobutanes. A formal synthesis of (±)-grandisol is described.
摘要
不饱和八元内酯经历脱羧和非脱羧的跨环 Ireland-Claisen 重排反应，生成取代的乙烯基环丁烷。（±）-grandisol 的一个正式合成被描述。
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