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离子液体在电化学传感中的应用研究进展。

Recent advances in the use of ionic liquids for electrochemical sensing.

机构信息

Nanochemistry Research Institute, Department of Chemistry, Curtin University, Perth, Australia.

出版信息

Analyst. 2011 Dec 7;136(23):4871-82. doi: 10.1039/c1an15699c. Epub 2011 Oct 20.

Abstract

Ionic Liquids are salts that are liquid at (or just above) room temperature. They possess several advantageous properties (e.g. high intrinsic conductivity, wide electrochemical windows, low volatility, high thermal stability and good solvating ability), which make them ideal as non-volatile electrolytes in electrochemical sensors. This mini-review article describes the recent uses of ionic liquids in electrochemical sensing applications (covering the last 3 years) in the context of voltammetric sensing at solid/liquid, liquid/liquid interfaces and carbon paste electrodes, as well as their use in gas sensing, ion-selective electrodes, and for detecting biological molecules, explosives and chemical warfare agents. A comment on the future direction and challenges in this field is also presented.

摘要

离子液体是指在室温(或略高于室温)下呈液态的盐。它们具有许多优点(例如,高固有电导率、宽电化学窗口、低挥发性、高热稳定性和良好的溶解能力),这使它们成为电化学传感器中理想的非挥发性电解质。本文综述了近 3 年来离子液体在电化学传感应用中的最新用途(包括在固/液、液/液界面和碳糊电极上的伏安传感),以及它们在气体传感、离子选择性电极以及用于检测生物分子、爆炸物和化学战剂方面的应用。还对该领域未来的发展方向和挑战进行了评论。

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