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基于离子液体的光学和电化学二氧化碳传感器。

Ionic Liquid-Based Optical and Electrochemical Carbon Dioxide Sensors.

作者信息

Behera Kamalakanta, Pandey Shubha, Kadyan Anu, Pandey Siddharth

机构信息

Department of Chemistry, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016, India.

Department of Science and Technology, Ministry of Science and Technology, Technology Bhawan, New Mehrauli Road, New Delhi 110016, India.

出版信息

Sensors (Basel). 2015 Dec 4;15(12):30487-503. doi: 10.3390/s151229813.

Abstract

Due to their unusual physicochemical properties (e.g., high thermal stability, low volatility, high intrinsic conductivity, wide electrochemical windows and good solvating ability), ionic liquids have shown immense application potential in many research areas. Applications of ionic liquid in developing various sensors, especially for the sensing of biomolecules, such as nucleic acids, proteins and enzymes, gas sensing and sensing of various important ions, among other chemosensing platforms, are currently being explored by researchers worldwide. The use of ionic liquids for the detection of carbon dioxide (CO₂) gas is currently a major topic of research due to the associated importance of this gas with daily human life. This review focuses on the application of ionic liquids in optical and electrochemical CO₂ sensors. The design, mechanism, sensitivity and detection limit of each type of sensor are highlighted in this review.

摘要

由于其独特的物理化学性质(如高热稳定性、低挥发性、高本征电导率、宽电化学窗口和良好的溶剂化能力),离子液体在许多研究领域都显示出巨大的应用潜力。目前,全球研究人员正在探索离子液体在开发各种传感器中的应用,特别是用于检测生物分子,如核酸、蛋白质和酶,以及在气体传感和各种重要离子传感等其他化学传感平台中的应用。由于二氧化碳(CO₂)气体与人类日常生活的相关性,目前使用离子液体检测该气体是一个主要的研究课题。本综述重点关注离子液体在光学和电化学CO₂传感器中的应用。本文突出了每种类型传感器的设计、机理、灵敏度和检测限。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e5e1/4721733/04d5f3c5d99b/sensors-15-29813-g001.jpg

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