Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Ohmiya, Asahi, Osaka, Japan.
Molecules. 2011 Oct 27;16(11):9067-76. doi: 10.3390/molecules16119067.
Linear polystyrene-stabilized PdO nanoparticles (PS-PdONPs) were prepared by thermal decomposition of Pd(OAc)(2) in the presence of polystyrene. X-ray diffraction (XRD) and transmission electron microscopy (TEM) indicated the production of PdO nanoparticles. The loading of palladium was determined by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). PS-PdONPs exhibited high catalytic activity for Mizoroki-Heck reactions under air in water and could be recycled without loss of activity.
线性聚苯乙烯稳定的 PdO 纳米粒子（PS-PdONPs）通过 Pd(OAc)(2) 在聚苯乙烯存在下的热分解制备。X 射线衍射（XRD）和透射电子显微镜（TEM）表明 PdO 纳米粒子的生成。钯的负载量通过电感耦合等离子体原子发射光谱（ICP-AES）确定。PS-PdONPs 在空气中的水中对 Mizoroki-Heck 反应表现出高催化活性，并且可以在不损失活性的情况下回收。
