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一种基于首例{Nb10V4O40(OH)2}(12-)簇和铜离子的空前的有机-无机杂化材料。

An unprecedented organic-inorganic hybrid based on the first {Nb10V4O40(OH)2}(12-) clusters and copper cations.

机构信息

Institute of Functional Material Chemistry, Key Lab of Polyoxometalate, Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024 Jilin, People's Republic of China.

出版信息

Chem Commun (Camb). 2012 Jan 4;48(1):103-5. doi: 10.1039/c1cc15684e. Epub 2011 Nov 4.

DOI:10.1039/c1cc15684e
PMID:22057477
Abstract

An unprecedented organic-inorganic hybrid {[Cu(6)L(6)(H(2)O)(3)][Nb(10)V(4)O(40)(OH)(2)]}(2)·13H(2)O (1) (L = 1,10-phenanthroline) containing the unreported {Nb(10)V(4)O(40)(OH)(2)}(12-) building blocks has been successfully synthesized and its photoluminescent properties, IR spectra, thermogravimetric analyses and single-crystal X-ray diffraction were investigated.

摘要

一种前所未有的有机-无机杂化{[Cu(6)L(6)(H(2)O)(3)][Nb(10)V(4)O(40)(OH)(2)]}(2)·13H(2)O(1)(L=1,10-菲咯啉),其中包含未报道的{Nb(10)V(4)O(40)(OH)(2)}(12-)建筑块,已被成功合成,并对其光致发光性质、红外光谱、热重分析和单晶 X 射线衍射进行了研究。

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