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双（μ(2)-2-苯氧基丙酸根-κO:O'）双[（1,10-菲咯啉-κN,N'）双（2-苯氧基丙酸根-κO,O'）镱（III）]

Bis(μ(2)-2-phen-oxy-propionato-κO:O')bis-[(1,10-phenanthroline-κN,N')bis-(2-phen-oxy-propionato-κO,O')ytterbium(III)].

作者信息

Shen Jin-Bei, Liu Jia-Lu, Zhao Guo-Liang

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1361. doi: 10.1107/S1600536811036105. Epub 2011 Sep 14.

DOI:10.1107/S1600536811036105
PMID:22058692
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3201286/
Abstract

In the centrosymmetric binuclear title complex, [Yb(2)(C(9)H(9)O(3))(6)(C(12)H(8)N(2))(2)], the two Yb(III) ions are linked by two 2-phen-oxy-propionate (L) groups in a bidentate bridging mode. Each Yb(III) ion is eight-coordinated by two O atoms from two bridging L ligands, four O atoms from two chelating L groups and two N atoms from one chelating phen mol-ecule in a distorted YbN(2)O(6) dodeca-hedral geometry.

摘要

在中心对称的双核标题配合物[Yb₂(C₉H₉O₃)₆(C₁₂H₈N₂)₂]中，两个Yb(III)离子通过两个2-苯氧基丙酸酯（L）基团以双齿桥联模式相连。每个Yb(III)离子在扭曲的YbN₂O₆十二面体几何构型中，由来自两个桥联L配体的两个O原子、来自两个螯合L基团的四个O原子以及来自一个螯合邻菲罗啉分子的两个N原子进行八配位。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/efe5/3201286/f2093c026d77/e-67-m1361-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/efe5/3201286/a2290c33b090/e-67-m1361-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/efe5/3201286/f2093c026d77/e-67-m1361-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/efe5/3201286/a2290c33b090/e-67-m1361-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/efe5/3201286/f2093c026d77/e-67-m1361-fig2.jpg

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本文引用的文献

1
Tetra-kis(μ(2)-2-phen-oxy-propionato)-κO,O':O';κO:O,O';κO:O'-bis-[(1,10-phenanthroline-κN,N')(2-phen-oxy-propionato-κO,O')gadolinium(III)].四-双（μ(2)-2-苯氧基丙酸根）-κO,O':O';κO:O,O';κO:O'-双-[(1,10-菲咯啉-κN,N')(2-苯氧基丙酸根-κO,O')钆(III)]
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1357. doi: 10.1107/S1600536811036130. Epub 2011 Sep 14.
2
Tetra-kis(μ(2)-2-phen-oxy-propionato)-κO,O':O';κO:O,O';κO:O'-bis-[(1,10-phenanthroline-κN,N')(2-phen-oxy-propionato-κO,O')cerium(III)].四-双（μ(2)-2-苯氧基丙酸根）-κO,O':O';κO:O,O';κO:O'-双-[(1,10-菲咯啉-κN,N')(2-苯氧基丙酸根-κO,O')铈(III)]
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1359-60. doi: 10.1107/S1600536811036129. Epub 2011 Sep 14.
3
Tetra-kis(μ-2-phen-oxy-propionato)-κO,O':O';κO:O,O',κO:O'-bis-[(1,10-phenanthroline-κN,N')(2-phen-oxy-propionato-κO,O')praseodymium(III)].四-双（μ-2-苯氧基丙酸根）-κO，O'：O'；κO：O，O'，κO：O'-双-[(1,10-菲咯啉-κN，N')(2-苯氧基丙酸根-κO，O')镨(III)]
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1321. doi: 10.1107/S1600536811034702. Epub 2011 Aug 31.
4
Tetra-kis(μ-2-phen-oxy-propionato)-κO,O':O';κO:O,O',κO:O'-bis-[(1,10-phenanthroline-κN,N')(2-phen-oxy-propionato-κO,O')dysprosium(III)].四（μ-2-苯氧基丙酸根）-κO，O'：O'；κO：O，O'，κO：O'-双[（1,10-菲咯啉-κN，N'）（2-苯氧基丙酸根-κO，O'）镝（III）]
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5
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Tetra-kis(μ(2)-2-phen-oxy-propionato)-κO,O':O';κO:O,O';κO:O'-bis-[(1,10-phenanthroline-κN,N')(2-phen-oxy-propionato-κO,O')lanthanum(III)].四-双（μ(2)-2-苯氧基丙酸根）-κO,O':O';κO:O,O';κO:O'-双-[(1,10-菲咯啉-κN,N')(2-苯氧基丙酸根-κO,O')镧(III)]
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