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链状聚[[(三苯基膦)铜(I)]-二-μ-碘代-[(三苯基膦)铜(I)]-μ-{1,2-双-[1-(吡啶-4-基)亚乙基]肼}]。

catena-Poly[[(triphenyl-phosphane)copper(I)]-di-μ-iodido-[(triphenyl-phosphane)copper(I)]-μ-{1,2-bis-[1-(pyridin-4-yl)ethyl-idene]hydrazine}].

作者信息

Fun Hoong-Kun, Loh Wan-Sin, Patra Goutam K, Mukherjee Anindita, Pal Pankaj K

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1389. doi: 10.1107/S1600536811036555. Epub 2011 Sep 14.

DOI:10.1107/S1600536811036555
PMID:22058699
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3201507/
Abstract

In the title coordination polymer, Cu(2)I(2)(C(14)H(14)N(4))(C(18)H(15)P)(2), the Cu(I) atom is coordinated by two I atoms, one P atom and one N atom in a fairly regular tetra-hedral arrangement. A crystallographic inversion centre generates a Cu(2)I(2) diamond with a Cu-Cu separation of 3.0120 (5) Å. The complete N,N'-(1-pyridin-4-yl-ethethyl-idene)-hydrazine mol-ecule is also generated by inversion symmetry, and this bridging ligand leads to [011] polymeric chains in the crystal structure.

摘要

在标题配位聚合物[Cu₂I₂(C₁₄H₁₄N₄)(C₁₈H₁₅P)₂]ₙ中，Cu(I)原子由两个I原子、一个P原子和一个N原子以相当规则的四面体排列方式配位。一个晶体学倒转中心生成了一个Cu₂I₂菱形，Cu-Cu间距为3.0120 (5) Å。完整的N,N'-（1-吡啶-4-基-亚乙基）-肼分子也由倒转对称性生成，并且这个桥联配体在晶体结构中导致了[011]聚合链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49d4/3201507/155f3171a51b/e-67-m1389-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49d4/3201507/ea33c0b37c70/e-67-m1389-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49d4/3201507/0f9f312847d7/e-67-m1389-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49d4/3201507/155f3171a51b/e-67-m1389-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49d4/3201507/ea33c0b37c70/e-67-m1389-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49d4/3201507/0f9f312847d7/e-67-m1389-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/49d4/3201507/155f3171a51b/e-67-m1389-fig3.jpg

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