Shi Qi-Ying, Zhang Guo-Chun, Zhou Chun-Sheng, Yang Qi
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1430. doi: 10.1107/S1600536811038591. Epub 2011 Sep 30.
In the title complex, [Co(C(6)H(5)N(2)O(2))(2)(H(2)O)(2)]·2H(2)O, the coordination geometry of the Co(2+) cation is distorted octa-hedral, with two N atoms and two O atoms from two 5-methyl-pyrazine-2-carboxyl-ate ligands in the equatorial plane. The two remaining coordination sites are occupied by two water mol-ecules. In addition, there are two uncoordinated water mol-ecules in the asymmetric unit. The crystal structure is stabilized by a network of O-H⋯O and O-H⋯N hydrogen-bonding inter-actions, forming a three-dimensional structure.
在标题配合物[Co(C₆H₅N₂O₂)₂(H₂O)₂]·2H₂O中,Co²⁺阳离子的配位几何构型为畸变八面体,两个N原子和两个O原子来自两个5-甲基吡嗪-2-羧酸酯配体,处于赤道平面。其余两个配位点由两个水分子占据。此外,不对称单元中有两个未配位的水分子。晶体结构通过O—H⋯O和O—H⋯N氢键相互作用网络得以稳定,形成三维结构。