二水合 -（5 - 甲基 - 吡嗪 - 2 - 羧酸根 - κN,O）铁（II）
Diaqua-(5-methyl-pyrazine-2-carboxyl-ato-κN,O)iron(II).
作者信息
Fan Guang, Sun Jia-Juan, Zhang Jun-Cai, Ma Zhan-Ying, Gao Sheng-Li
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 20;65(Pt 1):m107. doi: 10.1107/S1600536808042529.
Abstract
In the neutral title complex, [Fe(C(6)H(5)N(2)O(2))(2)(H(2)O)(2)], the coordination geometry aound the Fe(II) atom, which lies on an inversion centre, is distorted octa-hedral comprising two N atoms and two O atoms from two 5-methyl-pyrazine-2-carboxyl-ate ligands, and two water mol-ecules. The crystal structure is stabilized by a network of O-H⋯O hydrogen bonds, resulting in a two-dimensional supra-molecular structure.
摘要
在中性标题配合物[Fe(C₆H₅N₂O₂)₂(H₂O)₂]中，位于对称中心的Fe(II)原子的配位几何构型为畸变八面体，由来自两个5-甲基吡嗪-2-羧酸酯配体的两个N原子、两个O原子以及两个水分子组成。晶体结构通过O—H⋯O氢键网络得以稳定，形成二维超分子结构。
相似文献
1
Diaqua-(5-methyl-pyrazine-2-carboxyl-ato-κN,O)iron(II).二水合 -（5 - 甲基 - 吡嗪 - 2 - 羧酸根 - κN,O）铁（II）
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 20;65(Pt 1):m107. doi: 10.1107/S1600536808042529.
2
Bis(3-amino-pyrazine-2-carboxyl-ato-κN,O)diaqua-manganese(II).双（3-氨基-吡嗪-2-羧基-κN，O）二水合锰（II）
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 8;66(Pt 10):m1228. doi: 10.1107/S1600536810034835.
3
Diaqua-bis-(5-methyl-pyrazine-2-carboxyl-ato-κN,O)cobalt(II) dihydrate.二水合双（5-甲基-吡嗪-2-羧酸根-κN，O）钴（II）
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1430. doi: 10.1107/S1600536811038591. Epub 2011 Sep 30.
4
Diaqua-bis-(5-carb-oxy-1H-imidazole-4-carboxyl-ato-κN,O)iron(II).二水合双（5-羧基-1H-咪唑-4-羧基根-κN，O）铁（II）
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):m997. doi: 10.1107/S1600536811024779. Epub 2011 Jun 30.
5
catena-Poly[[[diaqua-nickel(II)]-μ-pyrazine-2-carboxyl-ato-silver(I)-μ-pyrazine-2-carboxyl-ato] nitrate dihydrate].链状聚[[[二水合镍（II）]-μ-吡嗪-2-羧酸根合银（I）-μ-吡嗪-2-羧酸根合]硝酸二水合物]
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):m689. doi: 10.1107/S1600536812018119. Epub 2012 Apr 28.
6
Diaqua-bis(pyridine-2-carboxyl-ato-κN,O)iron(II).二水合双（吡啶-2-羧酸根-κN,O）铁（II）
Acta Crystallogr Sect E Struct Rep Online. 2009 Feb 25;65(Pt 3):m315-6. doi: 10.1107/S1600536809005765.
7
A polymorph of diaqua-bis(pyrazine-2-carboxyl-ato-κN,O)copper(II).二水双（吡嗪-2-羧酸根-κN，O）铜（II）的一种多晶型物。
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 4;65(Pt 12):m1511. doi: 10.1107/S1600536809045371.
8
Diaqua-bis-(5-methyl-pyrazine-2-carboxyl-ato-κN,O)cadmium.二水合双（5-甲基-吡嗪-2-羧酸根-κN，O）镉
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1339-40. doi: 10.1107/S1600536811035045. Epub 2011 Sep 14.
9
trans-Diaqua-bis-[5-carb-oxy-2-(3-pyrid-yl)-1H-imidazole-4-carboxyl-ato-κN,O]cobalt(II).反式-二水合-双-[5-羧基-2-(3-吡啶基)-1H-咪唑-4-羧酸根合-κN,O]钴(II)
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):m1186. doi: 10.1107/S1600536811029618. Epub 2011 Aug 2.
10
Bis(3-amino-pyrazine-2-carboxyl-ato-κN,O)diaqua-manganese(II) mono-hydrate.一水合双（3-氨基吡嗪-2-羧酸根合-κN，O）二水合锰（II）
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 8;66(Pt 10):m1223. doi: 10.1107/S1600536810035233.
引用本文的文献
1
Diaqua-bis-(5-methyl-pyrazine-2-carboxyl-ato-κN,O)cadmium.二水合双（5-甲基-吡嗪-2-羧酸根-κN，O）镉
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1339-40. doi: 10.1107/S1600536811035045. Epub 2011 Sep 14.
本文引用的文献
1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
Zotero 插件