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聚[[二水双（2,2'-联吡啶-κN,N'）（μ(3)-5-羟基间苯二甲酸根-κO,O:O,O:O）（μ(3)-5-羟基间苯二甲酸根-κO,O:O:O）（μ(2)-5-羟基间苯二甲酸根-κO,O:O）二镝（III）]]二水合物

Poly[[diaquabis(2,2'-bipyridine-κN,N')(μ(3)-5-hydroxyisophthalato-κO,O:O,O:O)(μ(3)-5-hydroxy-isophthalato-κO,O:O:O)(μ(2)-5-hydroxyisophthalato-κO,O:O)didysprosium(III)] dihydrate].

作者信息

Zhang Yan-Lin

机构信息

School of Chemistry and Environment, South China Normal University, Guangzhou 510006, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1473-4. doi: 10.1107/S1600536811039080. Epub 2011 Sep 30.

DOI:10.1107/S1600536811039080
PMID:22058725
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3201354/
Abstract

The polymeric title compound, {[Dy(2)(C(8)H(4)O(5))(3)(C(10)H(8)N(2))(2)(H(2)O)(2)]·2H(2)O}(n), contains two independent Dy(III) ions, both of which are nine-coordinated in a distorted tricapped trigonal-prismatic geometry. One Dy(III) ion is coordinated by five 5-hy-droxy-isophthalate (hip) ligands and one 2,2'-bipyridine (bpy) ligand and the other by three hip ligands, one bpy ligand and two water mol-ecules. The Dy(III) ions are bridged by the carboxyl-ate groups of the hip ligands, forming a three-dimensional framework. O-H⋯O hydrogen bonds are present in the crystal structure.

摘要

聚合标题化合物{[Dy₂(C₈H₄O₅)₃(C₁₀H₈N₂)₂(H₂O)₂]·2H₂O}ₙ包含两个独立的Dy(III)离子，二者均以扭曲的三帽三角棱柱几何构型呈九配位。一个Dy(III)离子由五个5-羟基间苯二甲酸（hip）配体和一个2,2'-联吡啶（bpy）配体配位，另一个由三个hip配体、一个bpy配体和两个水分子配位。Dy(III)离子由hip配体的羧酸根基团桥连，形成三维骨架。晶体结构中存在O-H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0348/3201354/9cb7092d61b0/e-67-m1473-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0348/3201354/bab1f1ac9f0a/e-67-m1473-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0348/3201354/9cb7092d61b0/e-67-m1473-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0348/3201354/bab1f1ac9f0a/e-67-m1473-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0348/3201354/9cb7092d61b0/e-67-m1473-fig2.jpg

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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.