Padayachy Kamentheren, Mgcima Zolani, Fernandes Manuel A, Marques Helder M, de Sousa Alvaro S
School of Chemistry, Molecular Sciences Institute, University of the Witwatersrand, Private Bag 3, Wits 2050, Johannesburg, South Africa.
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):o2594. doi: 10.1107/S1600536811035598. Epub 2011 Sep 14.
In the title compound, C(4)H(10)NO(+)·Br(-), which was synthesized by dehydration of diethano-lamine with HBr, morpholinium and bromide ions are linked into chains by N-H⋯Br hydrogen bonds describing a C(2) (1)(4) graph-set motif. Weaker bifurcated N-H⋯Br inter-actions join centrosymmetrically related chains through alternating binary graph-set R(4) (2)(8) and R(2) (2)(4) motifs, to form ladders along [100]. In addition, C-H⋯O inter-actions between centrosymmetric morpholinium cations link ladders, viaFormula: see text motifs, to yield sheets parallel to (101), which in turn are crosslinked by weak C-H⋯O inter-actions, related across a glide plane, to form a three-dimensional network.
在标题化合物C₄H₁₀NO⁺·Br⁻中，它是由二乙醇胺与HBr脱水合成的，吗啉鎓离子和溴离子通过N-H⋯Br氢键连接成链，描述了一个C(2) (1)(4) 图集 motif。较弱的分叉N-H⋯Br相互作用通过交替的二元图集R(4) (2)(8) 和R(2) (2)(4) motif将中心对称相关的链连接起来，沿着[100]形成梯子。此外，中心对称的吗啉鎓阳离子之间的C-H⋯O相互作用通过公式：见正文 motif连接梯子，产生平行于(101)的片层，这些片层又通过弱的C-H⋯O相互作用在滑移面两侧相关联而交联，形成三维网络。
