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(Z)-3-(2,4-二氯苯基)-2-[(2-甲酰基苯氧基)甲基]丙烯酸甲酯

(Z)-Methyl 3-(2,4-dichloro-phen-yl)-2-[(2-formyl-phen-oxy)meth-yl]acrylate.

作者信息

Gangadharan Rajeswari, Sethusankar K, Selvakumar Raman, Bakthadoss Manickam

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):o2738. doi: 10.1107/S1600536811037925. Epub 2011 Sep 30.

DOI:10.1107/S1600536811037925
PMID:22058801
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3201315/
Abstract

In the title compound, C(18)H(14)Cl(2)O(4), the mean planes of the methyl acrylate unit and the phenyl ring of the benzaldehyde are approximately orthogonal to each other, making a dihedral angle of 83.31 (6)°. The O atom of the aldehyde group is displaced significantly from the phenyl ring plane by 0.226 (2) Å. The methyl acrylate group adopts an E conformation. In the crystal, inversion dimers linked by pairs of C-H⋯O hydrogen bonds generate R(2) (2)(24) loops.

摘要

在标题化合物C₁₈H₁₄Cl₂O₄中,丙烯酸甲酯单元的平均平面与苯甲醛的苯环平面大致相互正交,二面角为83.31(6)°。醛基的O原子相对于苯环平面显著位移0.226(2)Å。丙烯酸甲酯基团呈E构象。在晶体中,通过成对的C—H⋯O氢键连接的反演二聚体形成R₂²(24)环。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5c18/3201315/3979ac5edfbb/e-67-o2738-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5c18/3201315/81315467f972/e-67-o2738-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5c18/3201315/3979ac5edfbb/e-67-o2738-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5c18/3201315/81315467f972/e-67-o2738-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5c18/3201315/3979ac5edfbb/e-67-o2738-fig2.jpg

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