Kanu Godwin, Lalancette Roger A, Vitale Dale E
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):o2522. doi: 10.1107/S1600536811034052. Epub 2011 Aug 31.
In the title mol-ecule, C(19)H(13)N, the angle between the mean planes of the naphthalene and quinoline ring systems is 68.59 (2)°. The compound is of inter-est with respect to its potential for spontaneous resolution. In the crystal structure, the R and S isomers are arranged in alternating homochiral layers. The mol-ecules of a given layer are oriented with their major axes (i.e. the axis perpendicular to the interannular bond) in the same direction and their naphthalene and quinoline ring systems are arranged parallel. Like the configurations, this orientation alternates in adjacent layers.
在标题分子C₁₉H₁₃N中,萘环和喹啉环体系的平均平面之间的夹角为68.59 (2)°。该化合物因其自发拆分的潜力而备受关注。在晶体结构中,R和S异构体以交替的同手性层排列。给定层中的分子其长轴(即垂直于环间键的轴)方向相同,且它们的萘环和喹啉环体系平行排列。与构型一样,这种取向在相邻层中交替。