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2,4-二氯-N-(2,6-二甲基苯基)苯磺酰胺

2,4-Dichloro-N-(2,6-dimethyl-phen-yl)benzene-sulfonamide.

作者信息

Rodrigues Vinola Z, Foro Sabine, Gowda B Thimme

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):o2691. doi: 10.1107/S1600536811037767. Epub 2011 Sep 20.

DOI:10.1107/S1600536811037767
PMID:22064772
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3201408/
Abstract

In the crystal of the title compound, C(14)H(13)Cl(2)NO(2)S, the N-H bond in the C-SO(2)-NH-C segment orients itself away from the two ortho-methyl groups in the aniline benzene ring and towards the ortho-chloro group of the sulfonyl benzene ring. The mol-ecule is bent at the S atom with a C-SO(2)-NH-C torsion angle of -100.48 (18)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 69.6 (1)°. Inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into infinite chains.

摘要

在标题化合物C(14)H(13)Cl(2)NO(2)S的晶体中，C-SO(2)-NH-C片段中的N-H键远离苯胺苯环中的两个邻甲基，而朝向磺酰苯环的邻氯基团。分子在S原子处弯曲，C-SO(2)-NH-C扭转角为-100.48 (18)°。磺酰苯环和苯胺苯环彼此倾斜69.6 (1)°。分子间的N-H⋯O氢键将分子连接成无限链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d994/3201408/db84874fb960/e-67-o2691-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d994/3201408/ffbcf12f3530/e-67-o2691-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d994/3201408/db84874fb960/e-67-o2691-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d994/3201408/ffbcf12f3530/e-67-o2691-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d994/3201408/db84874fb960/e-67-o2691-fig2.jpg

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