Arumugam Sri Ranjini, Dasary Samuel S R, Venkatraman Ramaiyer, Yu Hongtao, Fronczek Frank R
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1409-10. doi: 10.1107/S1600536811037627. Epub 2011 Sep 30.
The title compound, [Sn(C(6)H(5))(2)(C(12)H(11)N(4)S(2))Cl]·CH(4)O, is formed during the reaction between 2-acetyl-thia-zole 4-phenyl-thio-semicarbazone (Hacthptsc) and diphenyl-tin(IV) dichloride in methanol. In the crystal structure, the Sn atom exhibits an octa-hedral geometry with the [N(2)S] anionic tridentate thio-semicarbazone ligand having chloride trans to the central N and the two phenyl groups trans to each other. The Sn-Cl distance is 2.5929 (6), Sn-S is 2.4896 (6) and Sn-N to the central N is 2.3220 (16) Å. The MeOH mol-ecules link the Sn complexes into one-dimensional chains via N-H⋯O and O-H⋯Cl hydrogen bonds.
标题化合物[Sn(C₆H₅)₂(C₁₂H₁₁N₄S₂)Cl]·CH₄O是在2-乙酰基噻唑4-苯基硫代氨基脲（Hacthptsc）与二苯基二氯化锡（IV）在甲醇中的反应过程中形成的。在晶体结构中，Sn原子呈现八面体几何构型，[N₂S]阴离子三齿硫代氨基脲配体中，氯与中心N原子反位，两个苯基相互反位。Sn-Cl键长为2.5929 (6) Å，Sn-S键长为2.4896 (6) Å，Sn与中心N原子的键长为2.3220 (16) Å。甲醇分子通过N-H⋯O和O-H⋯Cl氢键将Sn配合物连接成一维链。
