Asatkar Ashish K, Verma Vinay K, Jain Tripti A, Singh Rajendra, Gupta Sushil K, Butcher Ray J
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):o2724-5. doi: 10.1107/S1600536811036622. Epub 2011 Sep 30.
The title compound, C(46)H(40)N(4)O(2)·0.33C(6)H(12), was obtained unintentionally as a product of an attempted synthesis of a cadmium(II) complex of the [2,6-{PhSe(CH(2))(2)N=CPh}(2)C(6)H(2)(4-Me)(OH)] ligand. The full tetra-imino-diphenol macrocyclic ligand is generated by the application of an inversion centre. The macrocyclic ligand features strong intra-molecular O-H⋯N hydrogen bonds. The dihedral angles formed between the phenyl ring incorporated within the macrocycle and the peripheral phenyl rings are 82.99 (8) and 88.20 (8)°. The cyclo-hexane solvent mol-ecule lies about a site of [Formula: see text] symmetry. Other solvent within the lattice was disordered and was treated with the SQUEEZE routine [Spek (2009). Acta Cryst. D65, 148-155].
标题化合物C(46)H(40)N(4)O(2)·0.33C(6)H(12)是在尝试合成[2,6-{PhSe(CH(2))(2)N=CPh}(2)C(6)H(2)(4-Me)(OH)]配体的镉(II)配合物时意外得到的产物。完整的四亚氨基二酚大环配体是通过应用对称中心生成的。大环配体具有很强的分子内O-H⋯N氢键。大环内所含苯环与外围苯环之间形成的二面角分别为82.99 (8)°和88.20 (8)°。环己烷溶剂分子位于一个具有[化学式：见原文]对称性的位点。晶格中的其他溶剂无序，用SQUEEZE程序[Spek (2009). Acta Cryst. D65, 148 - 155]处理。
