• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

链状聚[[二水合锶]-双-(μ-喹啉-3-羧酸根)]

catena-Poly[[diaqua-strontium]-bis-(μ-quinoline-3-carboxyl-ato)].

作者信息

Miao Dong-Liang, Li Shi-Jie, Song Wen-Dong, Ma Xiao-Tian, Li Xiao-Fei

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1386-7. doi: 10.1107/S1600536811036610. Epub 2011 Sep 14.

DOI:10.1107/S1600536811036610
PMID:22065503
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3201418/
Abstract

The title compound, Sr(C(10)H(6)NO(2))(2)(H(2)O)(2), contains an eight-coordinate Sr(II) ion displaying a distorted square-anti-prismatic geometry, two quinoline-3-carboxyl-ate ligands and two terminal water mol-ecules. The Sr(II) atom is surrounded by six carboxyl-ate O atoms from four separate quinoline-3-carboxyl-ate ligands and two O atoms from two coordinated water mol-ecules. The bridging carboxyl-ate O atoms [Sr-O = 2.498 (3) and 2.495 (3) Å] link Sr(II) atoms, forming a chain substructure extending along the c axis. The chains are linked by O-H⋯N and O-H⋯O hydrogen bonds, giving a three-dimensional framework structure.

摘要

标题化合物[Sr(C₁₀H₆NO₂)₂(H₂O)₂]ₙ包含一个八配位的Sr(II)离子，呈现出扭曲的四方反棱柱几何构型，两个喹啉-3-羧酸根配体和两个端基水分子。Sr(II)原子被来自四个不同喹啉-3-羧酸根配体的六个羧酸根O原子以及来自两个配位水分子的两个O原子所包围。桥连的羧酸根O原子[Sr - O = 2.498 (3) 和2.495 (3) Å]连接Sr(II)原子，形成沿c轴延伸的链状子结构。这些链通过O - H⋯N和O - H⋯O氢键相连，形成三维骨架结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/10cd/3201418/cf23eaf97195/e-67-m1386-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/10cd/3201418/2e82809af804/e-67-m1386-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/10cd/3201418/ee0014f2338f/e-67-m1386-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/10cd/3201418/cf23eaf97195/e-67-m1386-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/10cd/3201418/2e82809af804/e-67-m1386-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/10cd/3201418/ee0014f2338f/e-67-m1386-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/10cd/3201418/cf23eaf97195/e-67-m1386-fig3.jpg

相似文献

1
catena-Poly[[diaqua-strontium]-bis-(μ-quinoline-3-carboxyl-ato)].链状聚[[二水合锶]-双-(μ-喹啉-3-羧酸根)]
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1386-7. doi: 10.1107/S1600536811036610. Epub 2011 Sep 14.
2
catena-Poly[[diaqua-calcium(II)]-bis-(μ-quinoline-3-carboxyl-ato)].链状聚[[二水合钙（II）]-双-（μ-喹啉-3-羧酸根）]
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 23;66(Pt 11):m1441-2. doi: 10.1107/S1600536810039401.
3
Crystal structures of -poly[[μ-aqua-di-aqua(μ-2-methyl-propano-ato-κ :,':')calcium] 2-methyl-propano-ate dihydrate], -poly[[μ-aqua-di-aqua-(μ-2-methyl-propano-ato-κ :,':')strontium] 2-methyl-propano-ate dihydrate] and -poly[[μ-aqua-di-aqua-(μ-2-methyl-propano-ato-κ :,':')(calcium/strontium)] 2-methyl-propano-ate dihydrate].-聚[[μ-水合-二水合（μ-2-甲基丙酸根-κO1，O2'）钙]·2-甲基丙酸盐二水合物]、-聚[[μ-水合-二水合（μ-2-甲基丙酸根-κO1，O2'）锶]·2-甲基丙酸盐二水合物]以及-聚[[μ-水合-二水合（μ-2-甲基丙酸根-κO1，O2'）（钙/锶）]·2-甲基丙酸盐二水合物]的晶体结构
Acta Crystallogr E Crystallogr Commun. 2020 Sep 25;76(Pt 10):1684-1688. doi: 10.1107/S2056989020012888. eCollection 2020 Oct 1.
4
Poly[[diaqua-bis-[μ(4)-5-nitro-isophthalato-κ(4)O(1):O(1):O(3):O(3')]bis-[μ(3)-pyridine-4-carboxyl-ato-κ(3)O:O':N]tricobalt(II)] tetra-hydrate].聚[[二水合双-[μ(4)-5-硝基间苯二甲酸根合-κ(4)O(1):O(1):O(3):O(3')]双-[μ(3)-吡啶-4-羧酸根合-κ(3)O:O':N]三钴(II)]四水合物]
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):m451-2. doi: 10.1107/S1600536812011269. Epub 2012 Mar 21.
5
catena-Poly[[diaqua-strontium]-bis-(μ-2-bromo-benzoato)-κO,O':O';κO:O,O'].链状聚[[二水合锶]-双-(μ-2-溴苯甲酸根)-κO,O':O';κO:O,O']
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 4;65(Pt 12):m1500. doi: 10.1107/S1600536809045395.
6
Poly[[diaqua-(μ(4)-1H-benzimidazole-5,6-dicarboxyl-ato)strontium] monohydrate].聚[[二水合-(μ(4)-1H-苯并咪唑-5,6-二羧酸根)锶]一水合物]
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 21;65(Pt 12):m1643-4. doi: 10.1107/S1600536809048284.
7
Poly[diaqua-(μ(2)-oxalato-κO,O:O,O)(μ(2)-pyrazine-2-carboxyl-ato-κN,O:O,O')neodymium(III)].聚[二水合-(μ(2)-草酸根-κO,O:O,O)(μ(2)-吡嗪-2-羧酸根-κN,O:O,O')钕(III)]
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 12;65(Pt 9):m1065-6. doi: 10.1107/S1600536809031250.
8
catena-Poly[{di-μ-isonicotinato-bis[di-aqua-isonicotinatoeuropium(III)]}-μ-isonicotinato-[diisonicotinatocopper(II)]-μ-isonicotinato].链状聚[{双-μ-异烟酸根合双[二水合异烟酸根合铕(III)]}-μ-异烟酸根合-[二异烟酸根合铜(II)]-μ-异烟酸根]
Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 22;64(Pt 12):m1595-6. doi: 10.1107/S1600536808038476.
9
Poly[[diaqua-(μ(8)-benzene-1,2,4,5-tetra-carboxyl-ato)calciumzinc] monohydrate].聚[[二水合-(μ(8)-苯-1,2,4,5-四羧酸根)钙锌]一水合物]
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1150. doi: 10.1107/S1600536812034113. Epub 2012 Aug 4.
10
catena-Poly[[diaqua-(1,2,3-benzothia-diazole-7-carboxyl-ato-κO)copper(II)]-μ-1,2,3-benzothia-diazole-7-carboxyl-ato-κN:O].链状聚[[二水合-(1,2,3-苯并噻二唑-7-羧酸根-κO)铜(II)]-μ-1,2,3-苯并噻二唑-7-羧酸根-κN:O]
Acta Crystallogr Sect E Struct Rep Online. 2009 Sep 9;65(Pt 10):m1181-2. doi: 10.1107/S1600536809032036.

本文引用的文献

1
catena-Poly[[diaqua-calcium(II)]-bis-(μ-quinoline-3-carboxyl-ato)].链状聚[[二水合钙（II）]-双-（μ-喹啉-3-羧酸根）]
Acta Crystallogr Sect E Struct Rep Online. 2010 Oct 23;66(Pt 11):m1441-2. doi: 10.1107/S1600536810039401.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Cobalt(II) and nickel(II) complexes of quinoline-2-carboxylate.喹啉 - 2 - 羧酸盐的钴（II）和镍（II）配合物
Acta Crystallogr C. 2003 Jun;59(Pt 6):m228-30. doi: 10.1107/s0108270103008722. Epub 2003 May 20.