• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

聚[水合-[μ(5)-5-(异烟酰胺基)-间苯二甲酸根][μ(4)-5-(异烟酰胺基)-间苯二甲酸根]铈(III)银(I)]

Poly[aqua-[μ(5)-5-(isonicotinamido)-isophthalato][μ(4)-5-(isonicotinamido)-isophthalato]cerium(III)silver(I)].

作者信息

Nie Xue, Qu Jing-Nian

机构信息

Department of Chemistry and Materials Science, Hengyang, Hunan 421008, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1107-8. doi: 10.1107/S1600536811027668. Epub 2011 Jul 23.

DOI:10.1107/S1600536811027668
PMID:22090878
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3212176/
Abstract

The 4d-4f heteronuclear title complex, AgCe(C(14)H(8)N(2)O(5))(2)(H(2)O), has a three-dimensional framework structure, generated by the carboxyl-ate and pyridyl groups of the 5-(isonicotinamido)-isophthalate (INAIP) ligands bridging the metal ions. The Ce(III) atom is coordinated by eight O atoms from six INAIP ligands and a water mol-ecule in a distorted tricapped trigonal-prismatic geometry, while the Ag(I) atom has a distorted trigonal-planar AgN(2)O geometry. O-H⋯O and N-H⋯O hydrogen bonds and π-π inter-actions between the pyridine and benzene rings [centroid-centroid distances = 3.642 (4) and 3.624 (3) Å] stabilize the crystal structure.

摘要

4d - 4f异核标题配合物[AgCe(C₁₄H₈N₂O₅)₂(H₂O)]ₙ具有三维骨架结构，由5 -（异烟酰胺基）间苯二甲酸酯（INAIP）配体的羧酸根和吡啶基桥连金属离子形成。Ce(III)原子由来自六个INAIP配体的八个O原子和一个水分子配位，呈扭曲的三帽三角棱柱几何构型，而Ag(I)原子具有扭曲的三角平面AgN₂O几何构型。O - H⋯O和N - H⋯O氢键以及吡啶环和苯环之间的π - π相互作用[质心 - 质心距离 = 3.642 (4) 和3.624 (3) Å]稳定了晶体结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/27ac/3212176/2c5794b41ddd/e-67-m1107-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/27ac/3212176/7cc6fa1c6473/e-67-m1107-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/27ac/3212176/2c5794b41ddd/e-67-m1107-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/27ac/3212176/7cc6fa1c6473/e-67-m1107-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/27ac/3212176/2c5794b41ddd/e-67-m1107-fig2.jpg

相似文献

1
Poly[aqua-[μ(5)-5-(isonicotinamido)-isophthalato][μ(4)-5-(isonicotinamido)-isophthalato]cerium(III)silver(I)].聚[水合-[μ(5)-5-(异烟酰胺基)-间苯二甲酸根][μ(4)-5-(异烟酰胺基)-间苯二甲酸根]铈(III)银(I)]
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1107-8. doi: 10.1107/S1600536811027668. Epub 2011 Jul 23.
2
Poly[[aqua-[μ(5)-5-(isonicotinamido)-isophthalato][μ(4)-5-(isonicotinamido)-isophthalato]holmium(III)silver(I)] dihydrate].二水合聚[[水合-[μ(5)-5-(异烟酰胺基)-间苯二甲酸根][μ(4)-5-(异烟酰胺基)-间苯二甲酸根]钬(III)银(I)]]
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m1004-5. doi: 10.1107/S1600536812028620. Epub 2012 Jun 30.
3
Crystal structure of di-aqua-tris-(benzohydrazide-κ ,)(isophthalato-κ)samarium(III) nitrate.硝酸二水·三（苯甲酰肼-κN）（间苯二甲酸根-κO）钐（III）的晶体结构
Acta Crystallogr E Crystallogr Commun. 2018 Nov 6;74(Pt 12):1691-1694. doi: 10.1107/S2056989018015360. eCollection 2018 Dec 1.
4
Poly[[tetra-aqua-tetra-kis-[μ(3)-5-(pyridine-4-carboxamido)-isophthalato]cobalt(II)dierbium(III)] tetra-hydrate].聚[[四水合四-双-[μ(3)-5-(吡啶-4-甲酰胺基)-间苯二甲酸根合]钴(II)二铒(III)]]四水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1478-9. doi: 10.1107/S1600536811039948. Epub 2011 Oct 5.
5
Poly[[tetra-aqua-tetra-kis-[μ(3)-5-(pyridine-4-carboxamido)-isophthalato]-cobalt(II)-diholmium(III)] tetra-hydrate].聚[[四水合 - 四 - [μ(3)-5-(吡啶 - 4 - 甲酰胺基) - 间苯二甲酸根合] - 钴(II) - 二钬(III)]]四水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1574-5. doi: 10.1107/S1600536811042814. Epub 2011 Oct 22.
6
Poly[tetra-deca-aqua-tetra-kis-(μ(3)-1H-imidazole-4,5-dicarboxyl-ato)tetra-μ(3)-sulfato-cobalt(II)hexa-gadolinium(III)].聚[十四水四（μ(3)-1H-咪唑-4,5-二羧基）四-μ(3)-硫酸根合钴（II）六钆（III）]
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1060-1. doi: 10.1107/S1600536811026821. Epub 2011 Jul 9.
7
catena-Poly[4,4'-bipyridinium [[tetra-aqua-(pyridine-2,6-dicarboxyl-ato-κO,N,O)cerate(III)]-μ-pyridine-2,6-dicarboxyl-ato-κO:O,N,O-[(pyridine-2,6-dicarboxyl-ato-κO,N,O)cerate(III)]-μ-pyridine-2,6-dicarboxyl-ato-κO,N,O:O] penta-hydrate].链状聚[4,4'-联吡啶鎓[[四水合-(吡啶-2,6-二羧酸根-κO,N,O)铈(III)]-μ-吡啶-2,6-二羧酸根-κO:O,N,O-[(吡啶-2,6-二羧酸根-κO,N,O)铈(III)]-μ-吡啶-2,6-二羧酸根-κO,N,O:O]五水合物]
Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 12;67(Pt 3):m335-6. doi: 10.1107/S1600536811004995.
8
Poly[[hexa-aqua-(μ(2)-oxalato-κO,O:O,O)bis(μ(3)-pyridine-2,4-dicarboxyl-ato-κN,O:O:O)dicerium(III)] monohydrate].聚[[六水合-(μ(2)-草酸根-κO,O:O,O)双(μ(3)-吡啶-2,4-二羧酸根-κN,O:O:O)二铈(III)]]一水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):m21-2. doi: 10.1107/S1600536811051956. Epub 2011 Dec 7.
9
Di-μ-nicotinamide-κN:O;κO:N-bis-[aqua-bis-(4-bromo-benzoato)-κO;κO,O'-manganese(II)].二-μ-烟酰胺-κN:O;κO:N-双-[水-双-(4-溴苯甲酸根)-κO;κO,O'-锰(II)]
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1128-9. doi: 10.1107/S1600536811028492. Epub 2011 Jul 23.
10
Poly[aqua(μ(3)-5-aza-niumylisophthalato)-(μ-oxalato)neodymium(III)].聚[水合（μ(3)-5-氮杂异酞酸根）-（μ-草酸根）钕（III）]
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):m537. doi: 10.1107/S1600536812013554. Epub 2012 Apr 4.

引用本文的文献

1
Poly[[aqua-[μ(5)-5-(isonicotinamido)-isophthalato][μ(4)-5-(isonicotinamido)-isophthalato]holmium(III)silver(I)] dihydrate].二水合聚[[水合-[μ(5)-5-(异烟酰胺基)-间苯二甲酸根][μ(4)-5-(异烟酰胺基)-间苯二甲酸根]钬(III)银(I)]]
Acta Crystallogr Sect E Struct Rep Online. 2012 Jul 1;68(Pt 7):m1004-5. doi: 10.1107/S1600536812028620. Epub 2012 Jun 30.
2
Poly[[diaqua-bis-(μ(3)-3-carboxyl-ato-4-hy-droxy-benzene-sulfonato)-tri-μ(2)-pyrazine-tetra-silver(I)] dihydrate].聚[[二水合-双-(μ(3)-3-羧基-4-羟基苯磺酸根)-三-μ(2)-吡嗪-四银(I)]二水合物]
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1545. doi: 10.1107/S1600536811041626. Epub 2011 Oct 22.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
A 3D coordination framework based on linkages of nanosized hydroxo lanthanide clusters and copper centers by isonicotinate ligands.
Angew Chem Int Ed Engl. 2005 Feb 18;44(9):1385-8. doi: 10.1002/anie.200461424.
3
Synthesis, structures, and magnetic properties of novel mononuclear, tetranuclear, and 1D chain Mn(III) complexes involving three related asymmetrical trianionic ligands.涉及三种相关不对称三阴离子配体的新型单核、四核和一维链状锰（III）配合物的合成、结构及磁性
Inorg Chem. 2004 Apr 19;43(8):2736-44. doi: 10.1021/ic0348796.
4
Structural, electronic, and magnetic consequences of O-carbonyl vs O-alkoxy ester coordination in new dicopper complexes containing the Cu2(mu-Cl)2 core.含Cu2(μ-Cl)2核的新型二铜配合物中O-羰基与O-烷氧基酯配位的结构、电子和磁性后果
Inorg Chem. 2002 Nov 18;41(23):6153-60. doi: 10.1021/ic025568i.
5
Supramolecular isomerism in coordination compounds: nanoscale molecular hexagons and chains.配位化合物中的超分子异构现象：纳米级分子六边形和链状结构
J Am Chem Soc. 2002 Aug 28;124(34):9990-1. doi: 10.1021/ja027371v.