Li Xia, Du Ling-Zhi
Department of Chemistry and Chemical Engineering, Henan University of Urban Construction, Pingdingshan, Henan 467044, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1113. doi: 10.1107/S1600536811026341. Epub 2011 Jul 23.
In the title compound, [Fe(C(5)H(5))(C(15)H(11)N(2)O)], the cyclo-penta-dienyl rings are essentially eclipsed, and the dihedral angle between the cyclo-penta-dienyl ring planes is 0.632 (10)°. The Fe atom is slightly closer to the substituted cyclo-penta-dienyl ring, with an Fe-centroid distance of 1.6374 (3) Å [1.6494 (3) Å for the unsubstituted ring]. The amide group is essentially coplanar with the substituted cyclo-penta-dienyl ring, with an N-C(O)-C-C torsion angle of 2.3 (3)°.
在标题化合物[Fe(C₅H₅)(C₁₅H₁₁N₂O)]中，环戊二烯基环基本处于重叠构象，环戊二烯基环平面之间的二面角为0.632 (10)°。铁原子稍靠近取代的环戊二烯基环，Fe与环中心的距离为1.6374 (3) Å [未取代环的该距离为1.6494 (3) Å]。酰胺基团与取代的环戊二烯基环基本共平面，N - C(O) - C - C扭转角为2.3 (3)°。
