2-氨基苯胺鎓 6-羧基吡啶甲酸盐一水合物
2-Amino-anilinium 6-carb-oxy-picolinate monohydrate.
作者信息
Wang Yu-Tang, Gao De-Jiang
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o1893. doi: 10.1107/S1600536811025050. Epub 2011 Jul 2.
Abstract
In the title compound, C(6)H(9)N(2) (+)·C(7)H(4)NO(4) (-)·H(2)O, one amino group of diamino-benzene is protonated while one carb-oxy group of pyridine-2,6-dicarb-oxy-lic acid is deprotonated. In the anion, the CO(2) and CO(2)H groups make dihedral angles of 4.0 (5) and 8.7 (4)° with the pyridine ring. In the crystal, extensive N-H⋯O, N-H⋯N and O-H⋯O hydrogen bonds occur between anions, cations and water mol-ecules.
摘要
在标题化合物C(6)H(9)N(2) (+)·C(7)H(4)NO(4) (-)·H(2)O中，二氨基苯的一个氨基被质子化，而吡啶-2,6-二羧酸的一个羧基去质子化。在阴离子中，CO(2)和CO(2)H基团与吡啶环的二面角分别为4.0 (5)°和8.7 (4)°。在晶体中，阴离子、阳离子和水分子之间存在广泛的N-H⋯O、N-H⋯N和O-H⋯O氢键。
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