• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

溴化二水合乙基三苯基鏻

Ethyl-triphenyl-phospho-nium bromide dihydrate.

作者信息

Betz Richard, Gerber Thomas

机构信息

Nelson Mandela Metropolitan University, Summerstrand Campus, Department of Chemistry, University Way, Summerstrand, PO Box 77000, Port Elizabeth 6031, South Africa.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o1950. doi: 10.1107/S1600536811026559. Epub 2011 Jul 9.

DOI:10.1107/S1600536811026559
PMID:22090992
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3212335/
Abstract

In the crystal structure of the title hydrated bromide salt, C(20)H(20)P(+)·Br(-)·2H(2)O, O-H⋯Br and O-H⋯O hydrogen bonds as well as C-H⋯Br contacts connect the different components into a three-dimensional network. In the cation, the aromatic rings make dihedral angles of 55.24 (5), 76.16 (4) and 85.68 (4)°.

摘要

在标题水合溴化物盐C(20)H(20)P(+)·Br(-)·2H₂O的晶体结构中，O—H⋯Br和O—H⋯O氢键以及C—H⋯Br接触将不同组分连接成三维网络。在阳离子中，芳环形成的二面角分别为55.24 (5)°、76.16 (4)°和85.68 (4)°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/90f8/3212335/7b0c72a034ca/e-67-o1950-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/90f8/3212335/923ea8d8ddca/e-67-o1950-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/90f8/3212335/f811c3e771e2/e-67-o1950-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/90f8/3212335/7b0c72a034ca/e-67-o1950-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/90f8/3212335/923ea8d8ddca/e-67-o1950-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/90f8/3212335/f811c3e771e2/e-67-o1950-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/90f8/3212335/7b0c72a034ca/e-67-o1950-fig3.jpg

相似文献

1
Ethyl-triphenyl-phospho-nium bromide dihydrate.溴化二水合乙基三苯基鏻
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o1950. doi: 10.1107/S1600536811026559. Epub 2011 Jul 9.
2
(Furfuryl-amino)-triphenyl-phospho-nium bromide.（糠基氨基）三苯基溴化鏻
Acta Crystallogr Sect E Struct Rep Online. 2013 Jan 1;69(Pt 1):o118. doi: 10.1107/S1600536812050805. Epub 2012 Dec 22.
3
Isopropyl-triphenyl-phospho-nium bromide monohydrate.异丙基三苯基溴化鏻一水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):o3149. doi: 10.1107/S1600536811044849. Epub 2011 Nov 2.
4
2-(1,2-Dihydro-2-oxopyridin-3-yl)-1,3-benzothia-zol-3-ium bromide monohydrate.2-(1,2-二氢-2-氧代吡啶-3-基)-1,3-苯并噻唑-3-鎓溴化物一水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Jul 1;67(Pt 7):o1697. doi: 10.1107/S1600536811022847. Epub 2011 Jun 18.
5
(3-Chloro-prop-yl)triphenyl-phospho-nium bromide.（3-氯丙基）三苯基溴化鏻
Acta Crystallogr Sect E Struct Rep Online. 2012 Nov 1;68(Pt 11):o3115. doi: 10.1107/S1600536812042122. Epub 2012 Oct 13.
6
[4-(Methoxy-carbon-yl)benz-yl]triphenyl-phospho-nium bromide hemihydrate.[4-(甲氧基羰基)苄基]三苯基溴化鏻半水合物
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 11;64(Pt 2):o423. doi: 10.1107/S1600536808000184.
7
[4-(Bromo-methyl)-benz-yl]triphenyl-phospho-nium bromide acetonitrile monosolvate.[4-(溴甲基)-苄基]三苯基溴化鏻乙腈单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Nov 1;68(Pt 11):o3202. doi: 10.1107/S1600536812042341. Epub 2012 Oct 24.
8
1-Carboxymethyl-1'-carboxylatomethyl-3,3'-[p-phenylenebis(oxymethylene)]dipyridinium bromide dihydrate.1-羧甲基-1'-羧甲基-3,3'-[对亚苯基双(氧亚甲基)]二吡啶溴化物二水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 30;66(Pt 10):o2656. doi: 10.1107/S1600536810037748.
9
2,2'-Imino-diethanaminium 2,2'-(disulfanyldi-yl)dibenzoate dihydrate.2,2'-亚氨基二乙铵 2,2'-(二硫烷基二亚基)二苯甲酸酯二水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 27;66(Pt 3):o718. doi: 10.1107/S1600536810007117.
10
Crystal structure of 1,3-bis-(4-methyl-benz-yl)-1H-1,3-benzimidazol-3-ium bromide monohydrate.1,3 - 双 -（4 - 甲基 - 苄基）- 1H - 1,3 - 苯并咪唑 - 3 - 鎓溴化物一水合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Jan 1;71(Pt 1):o10-1. doi: 10.1107/S2056989014025857.

引用本文的文献

1
Crystal structure of N-[3-(di-methyl-aza-nium-yl)prop-yl]-N',N',N'',N''-tetra-methyl-N-(N,N,N',N'-tetra-methyl-form-am-id-in-ium-yl)-guanidinium dibromide hydroxide monohydrate.
Acta Crystallogr E Crystallogr Commun. 2015 Dec 24;71(Pt 12):o1078-9. doi: 10.1107/S2056989015024305. eCollection 2015 Dec 1.

本文引用的文献

1
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Graph-set analysis of hydrogen-bond patterns in organic crystals.有机晶体中氢键模式的图形集分析。
Acta Crystallogr B. 1990 Apr 1;46 ( Pt 2):256-62. doi: 10.1107/s0108768189012929.