2-（4-氟苯基）-1-苯基-1H-咪唑并[4,5-f][1,10]菲咯啉一水合物
2-(4-Fluoro-phen-yl)-1-phenyl-1H-imidazo[4,5-f][1,10]phenanthroline monohydrate.
作者信息
Rosepriya S, Venkatesh Perumal M, Thiruvalluvar A, Jayabharathi J, Butcher R J, Jasinski J P, Golen J A
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o1965. doi: 10.1107/S1600536811026328. Epub 2011 Jul 9.
In the title compound, C(25)H(15)FN(4)·H(2)O, the fused ring system is essentially planar [maximum deviation of 0.0822 (14) Å]. The imidazole ring makes dihedral angles of 76.83 (7) and 32.22 (7)° with the phenyl group attached to nitro-gen and the fluoro-benzene group to carbon, respectively. The dihedral angle between the two phenyl rings is 72.13 (7)°. Inter-molecular O-H⋯N, O-H⋯F, C-H⋯F, C-H⋯O and C-H⋯N hydrogen bonds are found in the crystal structure.
在标题化合物C(25)H(15)FN(4)·H(2)O中，稠环体系基本呈平面状[最大偏差为0.0822 (14) Å]。咪唑环与连接氮的苯基和连接碳的氟苯基团分别形成的二面角为76.83 (7)°和32.22 (7)°。两个苯环之间的二面角为72.13 (7)°。在晶体结构中发现了分子间的O-H⋯N、O-H⋯F、C-H⋯F、C-H⋯O和C-H⋯N氢键。
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