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(1S*,3S*,8S*,10S*)-10-Fluoro-15-oxa-tetra-cyclo-[6.6.1.0.0]penta-deca-5,12-dien-3-ol.

作者信息

Mehta Goverdhan, Sen Saikat

机构信息

Department of Organic Chemistry, Indian Institute of Science, Bangalore 560 012, Karnataka, India.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o1985. doi: 10.1107/S1600536811026857. Epub 2011 Jul 9.

DOI:10.1107/S1600536811026857
PMID:22091020
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3213441/
Abstract

The title compound, C(14)H(17)FO(2), was obtained from anti-4a,9a:8a,10a-diep-oxy-1,4,4a,5,8,8a,9,9a,10,10a-deca-hydro-anthra-cene via tandem hydrogen-fluoride-mediated epoxide ring-opening and transannular oxacyclization. With the two cyclo-hexene rings folded towards the oxygen bridge, the title tetra-cyclic fluoro-alcohol mol-ecule displays a conformation remin-iscent of a pagoda. The crystal packing is effected via inter-molecular O-H⋯O hydrogen bonds, which link the mol-ecules into a zigzag chain along the b axis.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b58/3213441/f8d1446dc6da/e-67-o1985-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b58/3213441/7d06aa58a816/e-67-o1985-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b58/3213441/e2ec05baf15c/e-67-o1985-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b58/3213441/70f0ba1ea704/e-67-o1985-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b58/3213441/8939562d60cb/e-67-o1985-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b58/3213441/f8d1446dc6da/e-67-o1985-fig5.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b58/3213441/7d06aa58a816/e-67-o1985-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b58/3213441/e2ec05baf15c/e-67-o1985-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b58/3213441/70f0ba1ea704/e-67-o1985-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b58/3213441/8939562d60cb/e-67-o1985-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1b58/3213441/f8d1446dc6da/e-67-o1985-fig5.jpg

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本文引用的文献

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