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7-甲氧基-1-(4-硝基苯甲酰基)萘-2-基 4-硝基苯甲酸酯

7-Meth-oxy-1-(4-nitro-benzo-yl)naph-thalen-2-yl 4-nitro-benzoate.

作者信息

Muto Toyokazu, Hijikata Daichi, Okamoto Akiko, Oike Hideaki, Yonezawa Noriyuki

机构信息

Department of Organic and Polymer Materials Chemistry, Tokyo University of Agriculture & Technology, Koganei, Tokyo 184-8588, Japan.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o2040. doi: 10.1107/S1600536811027619. Epub 2011 Jul 16.

Abstract

In the title compound, C(25)H(16)N(2)O(8), the dihedral angle between the naphthalene ring system and the benzene ring of the nitro-phenyl ketone unit is 82.64 (7)°. The bridging ester O-C(=O)-C plane makes dihedral angles of 42.12 (8) and 11.47 (9)°, respectively, with the naphthalene ring system and the benzene ring of the nitro-phenyl ester unit. In the crystal, two types of weak inter-molecular C-H⋯O inter-actions are observed.

摘要

在标题化合物C₂₅H₁₆N₂O₈中,萘环体系与硝基苯基酮单元的苯环之间的二面角为82.64(7)°。桥连酯O-C(=O)-C平面与萘环体系和硝基苯基酯单元的苯环分别形成42.12(8)°和11.47(9)°的二面角。在晶体中,观察到两种类型的弱分子间C-H⋯O相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/81a6/3213489/8ae2fbfa12f8/e-67-o2040-fig1.jpg

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