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N-(3-氯苯基)-N'-(3-甲基苯基)琥珀酰胺

N-(3-Chloro-phen-yl)-N'-(3-methyl-phen-yl)succinamide.

作者信息

Saraswathi B S, Foro Sabine, Gowda B Thimme

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o2077. doi: 10.1107/S1600536811028121. Epub 2011 Jul 23.

Abstract

The asymmetric unit of the title compound, C(17)H(17)ClN(2)O(2), contains one half-mol-ecule with a center of inversion at the mid-point of the central C-C bond. The amide N-H group is anti to the meta-chloro/methyl groups in the adjacent benzene rings. The dihedral angle between the benzene ring and the NH-C(O)-CH(2) segment is 43.5 (1)°. In the crystal, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into chains along the a axis. The methyl group and the Cl atom occupy the same position and were treated in a disorder model with site-occupation factors of 0.5 each.

摘要

标题化合物C(17)H(17)ClN(2)O(2)的不对称单元包含半个分子,其中心C-C键中点处存在一个反演中心。酰胺N-H基团与相邻苯环中的间氯/甲基呈反式。苯环与NH-C(O)-CH(2)片段之间的二面角为43.5 (1)°。在晶体中,分子间N-H⋯O氢键将分子沿a轴连接成链。甲基和Cl原子占据相同位置,并采用无序模型处理,占位因子均为0.5。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d0cf/3213520/9094167d8fb0/e-67-o2077-fig1.jpg

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