• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

2-[(4-甲酰基-苯基)(羟基)甲基]丙烯腈。

2-[(4-Formyl-phen-yl)(hy-droxy)meth-yl]acrylonitrile.

作者信息

Prasanna C M Sai, Sethusankar K, Rajesh R, Raghunathan R

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o2176. doi: 10.1107/S160053681102976X. Epub 2011 Jul 30.

DOI:10.1107/S160053681102976X
PMID:22091187
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3213610/
Abstract

In the title compound, C(11)H(9)NO(2), the mean planes formed by the phenyl and acryl group are almost orthogonal to each other, with a dihedral angle of 88.61 (7)°. The carbonitrile side chain is almost linear, the C-C-N angle being 179.54 (16)°. In the crystal, mol-ecules are linked by inter-molecular O-H⋯O inter-actions into infinite chains running parallel to the b axis.

摘要

在标题化合物C₁₁H₉NO₂中，苯基和丙烯基形成的平均平面彼此几乎正交，二面角为88.61（7）°。腈侧链几乎是线性的，C-C-N角为179.54（16）°。在晶体中，分子通过分子间O-H⋯O相互作用连接成平行于b轴的无限链。

相似文献

1
2-[(4-Formyl-phen-yl)(hy-droxy)meth-yl]acrylonitrile.2-[(4-甲酰基-苯基)(羟基)甲基]丙烯腈。
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):o2176. doi: 10.1107/S160053681102976X. Epub 2011 Jul 30.
2
2-{Hy-droxy[1-(4-meth-oxy-phen-yl)-4-oxo-3-phenyl-azetidin-2-yl]meth-yl}acrylonitrile.2-{羟基[1-(4-甲氧基苯基)-4-氧代-3-苯基氮杂环丁烷-2-基]甲基}丙烯腈
Acta Crystallogr Sect E Struct Rep Online. 2011 Sep 1;67(Pt 9):o2340. doi: 10.1107/S1600536811032247. Epub 2011 Aug 17.
3
3-[(2-Formyl-thio-phen-3-yl)(hy-droxy)meth-yl]thio-phene-2-carbaldehyde.3-[(2-甲酰基硫代苯-3-基)(羟基)甲基]噻吩-2-甲醛
Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):o182. doi: 10.1107/S1600536811052500. Epub 2011 Dec 21.
4
(E)-Methyl 2-({2-eth-oxy-6-[(E)-(hy-droxy-imino)-meth-yl]phen-oxy}meth-yl)-3-phenyl-acrylate.（E）-2-（{2-乙氧基-6-[(E)-(羟基亚氨基)甲基]苯氧基}甲基）-3-苯基丙烯酸甲酯
Acta Crystallogr Sect E Struct Rep Online. 2012 May 1;68(Pt 5):o1373. doi: 10.1107/S1600536812014596. Epub 2012 Apr 13.
5
(E)-Methyl 3-(4-chloro-phen-yl)-2-{2-[(E)-(hy-droxy-imino)-meth-yl]phen-oxy-meth-yl}acrylate.（E）-3-（4-氯苯基）-2-{2-[(E)-(羟基亚氨基)甲基]苯氧基甲基}丙烯酸甲酯
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):o2754. doi: 10.1107/S1600536811038372. Epub 2011 Sep 30.
6
3-(3-Chloro-2-hy-droxy-phen-yl)-1-phenyl-1H-pyrazole-4-carbaldehyde.3-（3-氯-2-羟基苯基）-1-苯基-1H-吡唑-4-甲醛
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):o2736. doi: 10.1107/S1600536811038025. Epub 2011 Sep 30.
7
Crystal structures of three carbazole derivatives: 12-ethyl-7-phenyl-sulfonyl-7-benzofuro[2,3-]carbazole, (1), 2-(4,5-dimeth-oxy-2-nitro-phen-yl)-4-hy-droxy-9-phenyl-sulfonyl-9-carbazole-3-carbaldehyde, (2), and 12-phenyl-7-phenyl-sulfonyl-7-benzofuro[2,3-]carbazole, (3).三种咔唑衍生物的晶体结构：12-乙基-7-苯基磺酰基-7-苯并呋喃并[2,3-]咔唑，（1）；2-（4,5-二甲氧基-2-硝基苯基）-4-羟基-9-苯基磺酰基-9-咔唑-3-甲醛，（2）；以及12-苯基-7-苯基磺酰基-7-苯并呋喃并[2,3-]咔唑，（3）。
Acta Crystallogr E Crystallogr Commun. 2016 Nov 4;72(Pt 12):1744-1750. doi: 10.1107/S2056989016016819. eCollection 2016 Dec 1.
8
4-Bromo-2-({4-[(hy-droxy-imino)-meth-yl]phen-yl}imino-meth-yl)phenol.4-溴-2-({4-[(羟基亚氨基)甲基]苯基}亚氨基甲基)苯酚
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 14;66(Pt 8):o2014. doi: 10.1107/S160053681002698X.
9
2-[(E)-({4-[(4,6-Dimethyl-pyrimidin-2-yl)sulfamo-yl]phen-yl}iminio)meth-yl]-6-hy-droxy-phenolate.2-[(E)-({4-[(4,6-二甲基嘧啶-2-基)氨磺酰基]苯基}亚氨基)甲基]-6-羟基苯酚盐
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):o2687. doi: 10.1107/S1600536812034757. Epub 2012 Aug 11.
10
4-Hy-droxy-3-[(4-hy-droxy-2-oxo-2H-3-chromen-yl)(3-thien-yl)meth-yl]-2H-chromen-2-one.4-羟基-3-[(4-羟基-2-氧代-2H-3-色烯基)(3-噻吩基)甲基]-2H-色烯-2-酮
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):o1037-8. doi: 10.1107/S1600536811011676. Epub 2011 Apr 7.

引用本文的文献

1
(E)-3-(2-Chloro-phen-yl)-2-[(2-formylphen-oxy)meth-yl]prop-2-ene-nitrile.（E）-3-（2-氯苯基）-2- [（2-甲酰基苯氧基）甲基]丙-2-烯腈
Acta Crystallogr Sect E Struct Rep Online. 2012 Apr 1;68(Pt 4):o934. doi: 10.1107/S1600536812008410. Epub 2012 Mar 3.
2
(E)-2-[(2-Formyl-phen-oxy)meth-yl]-3-(4-methyl-phen-yl)prop-2-ene-nitrile.（E）-2-[(2-甲酰基苯氧基)甲基]-3-(4-甲基苯基)丙烯腈
Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):o28. doi: 10.1107/S1600536811051415. Epub 2011 Dec 7.

本文引用的文献

1
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Novel combretastatin analogues effective against murine solid tumors: design and structure-activity relationships.对小鼠实体瘤有效的新型秋水仙素类似物：设计与构效关系
J Med Chem. 1998 Jul 30;41(16):3022-32. doi: 10.1021/jm980101w.