带有螺环吡啶-氨基膦配体的手性铱催化剂可实现β-芳基β-酮酯的高效不对称氢化。 - Suppr

Suppr

超能文献

Chiral iridium catalysts bearing spiro pyridine-aminophosphine ligands enable highly efficient asymmetric hydrogenation of β-aryl β-ketoesters.

作者信息

Xie Jian-Hua, Liu Xiao-Yan, Yang Xiao-Hui, Xie Jian-Bo, Wang Li-Xin, Zhou Qi-Lin

机构信息

State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China.

出版信息

Angew Chem Int Ed Engl. 2012 Jan 2;51(1):201-3. doi: 10.1002/anie.201105780. Epub 2011 Nov 16.

DOI:10.1002/anie.201105780

PMID:22095722

Abstract

摘要

相似文献

Chiral iridium catalysts bearing spiro pyridine-aminophosphine ligands enable highly efficient asymmetric hydrogenation of β-aryl β-ketoesters.

Angew Chem Int Ed Engl. 2012 Jan 2;51(1):201-3. doi: 10.1002/anie.201105780. Epub 2011 Nov 16.

Highly enantioselective hydrogenation of alpha-arylmethylene cycloalkanones catalyzed by iridium complexes of chiral spiro aminophosphine ligands.

J Am Chem Soc. 2010 Apr 7;132(13):4538-9. doi: 10.1021/ja100652f.

An additional coordination group leads to extremely efficient chiral iridium catalysts for asymmetric hydrogenation of ketones.

Angew Chem Int Ed Engl. 2011 Aug 1;50(32):7329-32. doi: 10.1002/anie.201102710. Epub 2011 Jul 12.

Enantioselective hydrogenation of alpha-aryloxy and alpha-alkoxy alpha,beta-unsaturated carboxylic acids catalyzed by chiral spiro iridium/phosphino-oxazoline complexes.

J Am Chem Soc. 2010 Jan 27;132(3):1172-9. doi: 10.1021/ja909810k.

Efficient asymmetric transfer hydrogenation of ketones in ethanol with chiral iridium complexes of spiroPAP ligands as catalysts.

Chem Commun (Camb). 2015 Apr 11;51(28):6123-5. doi: 10.1039/c5cc00479a.

Spiro[4,4]-1,6-nonadiene-based phosphine-oxazoline ligands for iridium-catalyzed enantioselective hydrogenation of ketimines.

Angew Chem Int Ed Engl. 2009;48(29):5345-9. doi: 10.1002/anie.200901630.

Highly Efficient Asymmetric Hydrogenation Catalyzed by Iridium Complexes with Tridentate Chiral Spiro Aminophosphine Ligands.

Acc Chem Res. 2023 Feb 7;56(3):332-349. doi: 10.1021/acs.accounts.2c00764. Epub 2023 Jan 23.

Direct asymmetric hydrogenation of α-keto acids by using the highly efficient chiral spiro iridium catalysts.

Chem Commun (Camb). 2014 Dec 28;50(100):15987-90. doi: 10.1039/c4cc07643e.

Catalytic asymmetric synthesis of aromatic spiroketals by spinphox/iridium(I)-catalyzed hydrogenation and spiroketalization of α,α'-bis(2-hydroxyarylidene) ketones.

Angew Chem Int Ed Engl. 2012 Jan 23;51(4):936-40. doi: 10.1002/anie.201106488. Epub 2011 Dec 14.

Asymmetric hydrogenation of quinazolinium salts catalysed by halide-bridged dinuclear iridium complexes bearing chiral diphosphine ligands.

Chem Commun (Camb). 2015 Mar 14;51(21):4380-2. doi: 10.1039/c5cc00258c.

引用本文的文献

A 13-million turnover-number anionic Ir-catalyst for a selective industrial route to chiral nicotine.

Nat Commun. 2023 Jun 22;14(1):3718. doi: 10.1038/s41467-023-39375-8.

Asymmetric Hydrative Aldol Reaction (HAR) via Vinyl-Gold Promoted Intermolecular Ynamide Addition to Aldehydes.

Angew Chem Int Ed Engl. 2023 Aug 1;62(31):e202305810. doi: 10.1002/anie.202305810. Epub 2023 Jun 23.

Asymmetric hydrogenation of exocyclic γ,δ-unsaturated β-ketoesters to functionalized chiral allylic alcohols dynamic kinetic resolution.

Chem Sci. 2021 Apr 29;12(22):7793-7799. doi: 10.1039/d1sc02044g.

Bioinspired enantioselective synthesis of crinine-type alkaloids iridium-catalyzed asymmetric hydrogenation of enones.

Chem Sci. 2017 Sep 1;8(9):6202-6206. doi: 10.1039/c7sc02112g. Epub 2017 Jul 3.

Access to optically pure β-hydroxy esters via non-enzymatic kinetic resolution by a planar-chiral DMAP catalyst.

Molecules. 2014 Sep 11;19(9):14273-91. doi: 10.3390/molecules190914273.

文献AI研究员

20分钟写一篇综述，助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型，支持多种主流文档格式。

立即体验

Chiral iridium catalysts bearing spiro pyridine-aminophosphine ligands enable highly efficient asymmetric hydrogenation of β-aryl β-ketoesters.

作者信息

Xie Jian-Hua, Liu Xiao-Yan, Yang Xiao-Hui, Xie Jian-Bo, Wang Li-Xin, Zhou Qi-Lin

机构信息

State Key Laboratory and Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China.

出版信息

Angew Chem Int Ed Engl. 2012 Jan 2;51(1):201-3. doi: 10.1002/anie.201105780. Epub 2011 Nov 16.

DOI:10.1002/anie.201105780

PMID:22095722

Abstract

摘要