Department of Energy Plant, Korea Institute of Machinery & Materials, 104 Sinseongno, Yuseong-gu, Daejeon 305-343, Korea.
Water Sci Technol. 2011;64(2):469-76. doi: 10.2166/wst.2011.566.
It was recently reported that a UK company has developed a naturally non-toxic magnetoferritin to act as a draw solute for drawing water in forward osmosis process. The gist of this technology is the utilization of the magnetic nanoparticle and high-gradient magnetic separation for draw solute separation and reuse. However, any demonstration on this technology has not been reported yet. In this study, a feasibility test of magnetic separation using magnetic nanoparticle was therefore performed to investigate the possibility of magnetic separation in water treatment such as desalination. Basically, a magnetic separation system consisted of a column packed with a bed of magnetically susceptible wools placed between the poles of electromagnet and Fe3O4 magnetic nanoparticle was used as a model nanoparticle. The effect of nanoparticle size to applied magnetic field in separation column was experimentally investigated and the magnetic field distribution in a magnet gap and the magnetic field gradient around stainless steel wool wire were analyzed through numerical simulation. The amount of magnetic nanoparticle captured in the separator column increased as the magnetic field strength and particle size increased. As a result, if magnetic separation is intended to be used for draw solute separation and reuse, both novel nanoparticle and large-scale high performance magnetic separator must be developed.
最近有报道称,一家英国公司开发了一种天然无毒的磁铁蛋白,用作正向渗透过程中的汲取溶质来汲取水。这项技术的要点是利用磁性纳米颗粒和高梯度磁分离来进行汲取溶质的分离和再利用。然而,目前尚未有关于该技术的任何示范。因此,本研究进行了使用磁性纳米颗粒的磁性分离可行性测试,以研究磁性分离在海水淡化等水处理中的可能性。基本上,使用了一个由置于电磁铁磁极之间的磁性羊毛床填充的柱体的磁性分离系统,并将 Fe3O4 磁性纳米颗粒用作模型纳米颗粒。实验研究了纳米颗粒尺寸对分离柱中施加磁场的影响,并通过数值模拟分析了磁铁间隙中的磁场分布和不锈钢羊毛线周围的磁场梯度。随着磁场强度和颗粒尺寸的增加,捕获在分离柱中的磁性纳米颗粒的数量增加。因此,如果要将磁性分离用于汲取溶质的分离和再利用,必须开发新型纳米颗粒和大型高性能磁分离机。