1,3,5-三苯基苯荧光团作为一种在水相介质中对 Cu2+具有选择性的传感器。
1,3,5-Triphenylbenzene fluorophore as a selective Cu2+ sensor in aqueous media.
机构信息
Program of Petrochemical and Polymer Science, Faculty of Science, Chulalongkorn University, Pathumwan, Bangkok 10330, Thailand.
出版信息
Chem Commun (Camb). 2012 Jan 7;48(2):293-5. doi: 10.1039/c1cc16148b. Epub 2011 Nov 18.
PMID:22101304
Abstract
Three water-soluble fluorophores are synthesized from 1,3,5-tris-(4'-iodophenyl)benzene. The compound with salicylate groups exhibits a selective fluorescent quenching by Cu(2+)via a static quenching mechanism. The addition of Triton X-100 improves the quantum efficiency of the fluorophore as well as the detection limit for Cu(2+) from 6.49 to 0.19 ppb.
摘要
三种水溶性荧光团是由 1,3,5-三（4'-碘苯基）苯合成的。具有水杨酸基团的化合物通过静态猝灭机制对 Cu(2+)表现出选择性荧光猝灭。加入 Triton X-100 提高了荧光团的量子效率以及 Cu(2+)的检测限，从 6.49 到 0.19 ppb。
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