Program of Petrochemical and Polymer Science, Faculty of Science, Chulalongkorn University, Pathumwan, Bangkok 10330, Thailand.
Chem Commun (Camb). 2012 Jan 7;48(2):293-5. doi: 10.1039/c1cc16148b. Epub 2011 Nov 18.
Three water-soluble fluorophores are synthesized from 1,3,5-tris-(4'-iodophenyl)benzene. The compound with salicylate groups exhibits a selective fluorescent quenching by Cu(2+)via a static quenching mechanism. The addition of Triton X-100 improves the quantum efficiency of the fluorophore as well as the detection limit for Cu(2+) from 6.49 to 0.19 ppb.
三种水溶性荧光团是由 1,3,5-三(4'-碘苯基)苯合成的。具有水杨酸基团的化合物通过静态猝灭机制对 Cu(2+)表现出选择性荧光猝灭。加入 Triton X-100 提高了荧光团的量子效率以及 Cu(2+)的检测限,从 6.49 到 0.19 ppb。