State Key Laboratory Breeding Base-Hebei Province Key Laboratory of Molecular Chemistry for Drug, Hebei University of Science & Technology, Shijiazhuang, 050018, People's Republic of China.
Org Biomol Chem. 2012 Jan 21;10(3):663-70. doi: 10.1039/c1ob06471a. Epub 2011 Nov 21.
Amorphous nickel powder (Ni(0)) was utilised as a catalyst under mild, aqueous, basic conditions for enhancing the sodium borohydride-mediated reduction of C-N multiple bonds such as oximes, imines, hydrazones and nitriles to produce the corresponding amines in good to excellent yields.
无定形镍粉(Ni(0))在温和、水相、碱性条件下作为催化剂,可增强硼氢化钠介导的 C-N 多重键(如肟、亚胺、腙和腈)的还原反应,以高产率得到相应的胺。