Synthesis and photoluminescence of nano-sized (Gd,Y)PO4:Eu3+ by solution combustion method.

We synthesized (Gd(1-x)Yx)(0.94)PO4:Eu(0.06) (0 < or = x < or = 1.0) phosphor powders of an ultra-fine size (approximately 23 nm), smooth surface, and spherical and regular morphologies by the solution combustion method. The crystallite sizes of the annealed (Gd(1-x)Yx)(0.94)PO4:Eu(0.06) phosphors with x = 0, 0.25, 0.5, 0.75, and 1.0 were 63.3, 62.3, 49.9, 45.1, and 43.3 nm, respectively. The photoluminescent characteristics of the phosphors were studied under vacuum ultraviolet excitation, depending on the Y3+ concentration. The intensity of the peaks corresponding to the red emission increased with increases in the Y3+ concentration. The Y(0.94)PO4:Eu(0.06) phosphor emitted the strongest intensity and the purest red color.