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双轮加热热解-傅里叶变换红外光谱-质谱联用技术(衍生气体分析)分析燃烧和热解过程中鼻烟烟粉

TG-FTIR-MS (Evolved Gas Analysis) of bidi tobacco powder during combustion and pyrolysis.

机构信息

Department of Chemistry, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia.

出版信息

J Hazard Mater. 2012 Jan 15;199-200:200-8. doi: 10.1016/j.jhazmat.2011.10.090. Epub 2011 Nov 7.

Abstract

Bidi smoke, a complex mixture of toxic and carcinogens chemicals causes a large and growing number of premature deaths in South Asian countries especially in India and Bangladesh. The evolved products during the thermal degradation of bidi tobacco powder (BTP) have been measured by using TG-FTIR-MS technique. The results revealed that the main gases and volatile products released during the combustion and pyrolysis of BTP are CO, CO(2), NH(3), HCN, NO, isoprene, formaldehyde, acetaldehyde, acrolein, etc. Still others such as nicotine, phenol, polyaromatic hydrocarbon and some tobacco specific nitrosamines are contained in submicron sized solid particles that are suspended in Bidi smoke. The intensity or the quantity of evolved products is higher during the combustion than pyrolysis of BTP. The evolved chemical data suggest that Bidi smoke is responsible for cancer of the throat, oral cavity, pharynx, larynx, lungs, esophagus, stomach, and liver.

摘要

比迪烟是一种复杂的有毒和致癌化学物质混合物,导致南亚国家,特别是印度和孟加拉国,越来越多的人过早死亡。使用 TG-FTIR-MS 技术测量了比迪烟烟草粉末(BTP)热降解过程中的衍生产物。结果表明,BTP 燃烧和热解过程中释放的主要气体和挥发性产物是 CO、CO(2)、NH(3)、HCN、NO、异戊二烯、甲醛、乙醛、丙烯醛等。还有一些物质,如尼古丁、苯酚、多环芳烃和一些烟草特异性亚硝胺,存在于悬浮在比迪烟中的亚微米级固体颗粒中。BTP 燃烧过程中产生的衍生产物的强度或数量高于热解过程。所产生的化学数据表明,比迪烟会导致喉咙、口腔、咽、喉、肺、食道、胃和肝的癌症。

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