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超声促进了一些新型稠合吡喃的合成。

Ultrasound promoted synthesis of some novel fused pyrans.

机构信息

Green Chemistry Department, National Research Centre, Dokki, Cairo 12622, Egypt.

出版信息

Ultrason Sonochem. 2012 May;19(3):491-7. doi: 10.1016/j.ultsonch.2011.10.008. Epub 2011 Nov 3.

Abstract

Novel fused pyrans were synthesized from the reaction of the tetrahydropyran-4-one with arylidine malononitriles. Different fused pyran derivatives were obtained from the mentioned reaction depending on type of catalyst used and type of energy used. Reactions were carried out under silent and ultrasonic conditions. In general, it was found that sometimes ultrasound irradiations change the reaction path in comparing with silent condition. In addition to improvement in reaction times, the products were obtained in high yields and their structures were determined by elemental analyses, spectral data.

摘要

新型稠合吡喃可由四氢吡喃-4-酮与亚胺基丙二腈的反应合成。根据所使用的催化剂和能量类型的不同,从上述反应中可以得到不同的稠合吡喃衍生物。反应在无声和超声条件下进行。一般来说,人们发现超声辐射有时会改变与无声条件相比的反应路径。除了反应时间的缩短,还可以高产率获得产物,其结构通过元素分析和光谱数据确定。

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