KAUST Advanced Membranes & Porous Materials Center, 4700 King Abdullah University of Science and Technology, Thuwal 23955-6900, Kingdom of Saudi Arabia.
Chem Commun (Camb). 2012 Feb 1;48(10):1455-7. doi: 10.1039/c1cc15962c. Epub 2011 Nov 28.
The uniqueness of the rht-MOF platform, based on the singular (3,24)-connected net, allows for the facile design and synthesis of functionalized materials for desired applications. Here we designed a nitrogen-rich trefoil hexacarboxylate (trigonal tri-isophthalate) ligand, which serves to act as the trigonal molecular building block while concurrently coding the formation of the targeted truncated cuboctahedral supermolecular building block (in situ), and enhancing the CO(2) uptake in the resultant rht-MOF.
rht-MOF 平台的独特性基于奇异的(3,24)-连接网络，允许为所需的应用轻松设计和合成功能化材料。在这里，我们设计了一种富氮三叶型六羧酸酯（三角三异苯二甲酸）配体，它不仅充当三角分子建筑块，同时还编码形成目标截断的立方八面体超分子建筑块（原位），并增强了所得 rht-MOF 中的 CO2 吸收。
