Los Alamos National Laboratory, Los Alamos, NM 87545, USA.
J Phys Condens Matter. 2012 Jan 11;24(1):015601. doi: 10.1088/0953-8984/24/1/015601. Epub 2011 Dec 2.
We report the synthesis, structure, and physical properties of single crystals of CePt(2)In(7). Single crystal x-ray diffraction analysis confirms the tetragonal I4/mmm structure of CePt(2)In(7) with unit cell parameters a = 4.5886(6) Å, c = 21.530(6) Å and V = 453.32(14) Å(3). The magnetic susceptibility, heat capacity, Hall effect and electrical resistivity measurements are all consistent with CePt(2)In(7) undergoing an antiferromagnetic order transition at T(N) = 5.5 K, which is field independent up to 9 T. Above T(N), the Sommerfeld coefficient of specific heat is γ ≈ 300 mJ mol(-1) K(-2), which is characteristic of an enhanced effective mass of itinerant charge carriers. The electrical resistivity is typical of heavy-fermion behavior and gives a residual resistivity ρ(0) ∼ 0.2 µΩ cm, indicating good crystal quality. CePt(2)In(7) also shows moderate anisotropy of the physical properties that is comparable to structurally related CeMIn(5) (M = Co, Rh, Ir) heavy-fermion superconductors.
我们报告了 CePt(2)In(7)单晶的合成、结构和物理性质。单晶 X 射线衍射分析证实了 CePt(2)In(7)具有四方 I4/mmm 结构,其晶胞参数为 a = 4.5886(6) Å, c = 21.530(6) Å 和 V = 453.32(14) Å(3)。磁化率、比热、霍尔效应和电阻率测量都表明 CePt(2)In(7)在 T(N) = 5.5 K 处经历反铁磁有序转变,该转变在 9 T 以下与磁场无关。在 T(N)以上,比热的 Sommerfeld 系数 γ≈300 mJ mol(-1) K(-2),这是巡游电荷载流子有效质量增强的特征。电阻率是典型的重费米子行为,给出残余电阻率 ρ(0)≈0.2 µΩ cm,表明晶体质量良好。CePt(2)In(7)还表现出与结构相关的 CeMIn(5)(M = Co、Rh、Ir)重费米子超导体相当的物理性质各向异性。