Joint Laboratory of Green Synthetic Chemistry, Department of Chemistry, University of Science and Technology of China, Hefei 230026, China.
Angew Chem Int Ed Engl. 2012 Jan 9;51(2):528-32. doi: 10.1002/anie.201106299. Epub 2011 Dec 1.
Easy access: An unprecedented copper-catalyzed cross-coupling reaction of the title compounds with diboron reagents is described (see scheme; Ts = 4-toluenesulfonyl). This reaction can be used to prepare both primary and secondary alkylboronic esters having diverse structures and functional groups. The resulting products would be difficult to access by other means.
本文描述了标题化合物与二硼试剂的前所未有的铜催化交叉偶联反应（见方案；Ts = 4-甲苯磺酰基）。该反应可用于制备具有各种结构和官能团的伯烷基和仲烷基硼酸酯。通过其他方法很难得到这些产物。
