Department of Chemistry, and Key Laboratory of UV Light-Emitting Materials and Technology of Ministry of Education, Northeast Normal University, 5268 Renmin Street, Changchun 130024, People' s Republic of China.
ACS Appl Mater Interfaces. 2012 Jan;4(1):424-30. doi: 10.1021/am201499r. Epub 2011 Dec 28.
One-dimensional In(2)O(3)-TiO(2) heteroarchitectures with high visible-light photocatalytic activity have been successfully obtained by a simple combination of electrospinning technique and solvothermal process. The as-obtained products were characterized by field emission scanning electron microscopy (FE-SEM), energy-dispersive X-ray (EDX) spectroscopy, transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and UV-vis spectra. The results revealed that the secondary In(2)O(3) nanostructures were successfully grown on the primary TiO(2) nanofibers substrates. Compared with the pure TiO(2) nanofibers, the obtained In(2)O(3)-TiO(2) heteroarchitectures showed enhancement of the visible-light photocatalytic activity to degrade rhodamine B (RB) because of the formation of heteroarchitectures, which might improve the separation of photogenerated electrons and holes derived from the coupling effect of TiO(2) and In(2)O(3) heteroarchitectures. Moreover, the In(2)O(3)-TiO(2) heteroarchitectures could be easily recycled without the decrease in the photocatalytic activity because of their one-dimensional nanostructural property.
一维的 In(2)O(3)-TiO(2) 异质结构具有高光催化活性,通过简单的静电纺丝技术和溶剂热工艺相结合成功获得。所得产物通过场发射扫描电子显微镜(FE-SEM)、能谱(EDX)、透射电子显微镜(TEM)、X 射线衍射(XRD)、X 射线光电子能谱(XPS)和紫外-可见光谱进行了表征。结果表明,二次 In(2)O(3) 纳米结构成功地生长在初级 TiO(2) 纳米纤维基底上。与纯 TiO(2) 纳米纤维相比,由于异质结构的形成,所获得的 In(2)O(3)-TiO(2) 异质结构表现出增强的可见光光催化活性,可降解罗丹明 B(RB),因为 TiO(2) 和 In(2)O(3) 异质结构的耦合效应可能提高光生电子和空穴的分离。此外,由于其一维纳米结构特性,In(2)O(3)-TiO(2) 异质结构可以很容易地回收,而不会降低光催化活性。