Department of Chemistry, Indian Institute of Technology Delhi, New Delhi, 110016, India.
Dalton Trans. 2012 Jan 28;41(4):1142-5. doi: 10.1039/c2dt12113a. Epub 2011 Dec 12.
Pd(4)Se and Pd(7)Se(4) nanoparticles (size 38-104 nm), protected by TOP, have been obtained for the first time using Pd(II) ligated with selenated primary and secondary amines (see 1 and 2) as single source precursors respectively. TEM, SEM, powder XRD and photoluminescence have been used to characterize them. 1 and 2 are also the first Pd(II)-selenoether complexes used for the synthesis of nanoparticles containing palladium and selenium.
首次使用分别与硒代伯胺和仲胺（参见 1 和 2）配位的 Pd(II)作为单源前体制备了尺寸为 38-104nm 的 Pd(4)Se 和 Pd(7)Se(4)纳米颗粒（TOP 保护）。TEM、SEM、粉末 XRD 和光致发光用于对它们进行表征。1 和 2 也是首次用于合成含钯和硒纳米颗粒的 Pd(II)-硒醚配合物。
