Department of Chemistry, KAIST, Daejeon 305-701, Korea.
Chem Asian J. 2012 Feb 6;7(2):406-11. doi: 10.1002/asia.201100679. Epub 2011 Dec 12.
We report unconventional magnetotransport properties of an individual Fe(1-x)Co(x)Si nanowire. We have studied the dependence of the resistivity on the angle between the directions of the magnetization and electrical current below the Curie temperature (T(C)). The observed anisotropic magnetoresistance (MR) ratio is negative, thereby indicating that the conduction electrons in a minority spin band of the Fe(1-x)Co(x)Si nanowire dominantly contribute to the transport. Unlike typical ferromagnets, positive MR is observed in the overall temperature range. MR curves are linear below T(C) and show a quadratic form above T(C), which can be explained by the change of density of states that arises as the band structures of the Fe(1-x)Co(x)Si nanowire shift under a magnetic field. The temperature dependence of the resistivity curve is sufficiently explained by the Kondo effect. The Kondo temperature of the Fe(1-x)Co(x)Si nanowire is lower than that of the bulk state due to suppression of the Kondo effect. The high single crystallinity of Fe(1-x)Co(x)Si nanowires allowed us to observe and interpret quite subtle variations in the prominent intrinsic transport properties.
我们报告了单个 Fe(1-x)Co(x)Si 纳米线的非传统磁输运性质。我们研究了在居里温度(T(C))以下,磁化方向和电流方向之间的角度对电阻率的依赖性。观察到的各向异性磁电阻(MR)比值为负,这表明 Fe(1-x)Co(x)Si 纳米线中少数自旋带的传导电子主要对输运有贡献。与典型的铁磁体不同,在整个温度范围内观察到正的 MR。在 T(C)以下,MR 曲线呈线性,在 T(C)以上呈二次形式,这可以通过能带结构在磁场下发生变化导致的态密度变化来解释。电阻率曲线的温度依赖性可以通过 Kondo 效应得到充分解释。由于 Kondo 效应的抑制,Fe(1-x)Co(x)Si 纳米线的 Kondo 温度低于体相状态。Fe(1-x)Co(x)Si 纳米线的高单晶度使我们能够观察和解释突出的内在输运性质中相当微妙的变化。