Department of Applied Chemistry, Osaka University, 2-1 Yamada-oka, Suita 565-0871, Japan.
Chem Commun (Camb). 2012 Feb 4;48(11):1641-3. doi: 10.1039/c2cc17007h. Epub 2011 Dec 14.
Chiral recognition abilities of the title host for (R)- and (S)-α-methyl-4-nitrobenzylamine were examined in the ground and excited states to give a relative affinity (K(R)/K(S)) of 2.16 by spectral titration and a relative rate constant (k(R)/k(S)) of 2.23 by fluorescence quenching, revealing that the quenching process is static and not enantiodifferentiating.
标题主体在基态和激发态对(R)-和(S)-α-甲基-4-硝基苯甲胺的手性识别能力进行了考察，通过光谱滴定得到相对亲和力（K(R)/K(S)）为 2.16，通过荧光猝灭得到相对速率常数（k(R)/k(S)）为 2.23，表明猝灭过程是静态的，不具有对映体选择性。
